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Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents. / Yevlampieva, N. P.; Bermeshev, M. V.; Vezo, O. S.; Chapala, P. P.; Il'yasova, Yu. V.

In: Polymer Science - Series A, Vol. 60, No. 2, 03.2018, p. 162-171.

Research output: Contribution to journal › Article › peer-review

Harvard

Yevlampieva, NP, Bermeshev, MV, Vezo, OS, Chapala, PP & Il'yasova, YV 2018, 'Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents', Polymer Science - Series A, vol. 60, no. 2, pp. 162-171. https://doi.org/10.1134/S0965545X18020050

APA

Yevlampieva, N. P., Bermeshev, M. V., Vezo, O. S., Chapala, P. P., & Il'yasova, Y. V. (2018). Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents. Polymer Science - Series A, 60(2), 162-171. https://doi.org/10.1134/S0965545X18020050

Vancouver

Yevlampieva NP, Bermeshev MV, Vezo OS, Chapala PP, Il'yasova YV. Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents. Polymer Science - Series A. 2018 Mar;60(2):162-171. https://doi.org/10.1134/S0965545X18020050

Author

Yevlampieva, N. P. ; Bermeshev, M. V. ; Vezo, O. S. ; Chapala, P. P. ; Il'yasova, Yu. V. / Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents. In: Polymer Science - Series A. 2018 ; Vol. 60, No. 2. pp. 162-171.

BibTeX

@article{dcef5d6ab8464f169ebbf0332d83dcaa,
title = "Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents",
abstract = "The molecular properties of the additive poly(bis(trimethylsilyl)tricyclononene) with the vicinal position of two side groups Si(CH3)(3) in the monomer unit are studied for the first time, and its conformational and kinetic properties are compared with those of the isomer with the geminal position of the same groups. Using the methods of static/dynamic light scattering and viscometry for the samples of the vicinal isomer, the hydrodynamic parameters of molecules are determined and their molecular mass dependences in toluene are ascertained. In addition, the Kuhn segment length of this isomer is estimated. The kinetic rigidity of vicinal and geminal isomers is evaluated by H-1 NMR relaxation from the mobility of protons in Si(CH3)(3) groups. The reasons behind different gas permeabilities of the films based on the polymers with the vicinal and geminal positions of Si(CH3)3 side groups in the monomer unit are discussed.",
keywords = "TRICYCLONONENES, QUADRICYCLANE, SEPARATION, POLYMERS, RIGIDITY",
author = "Yevlampieva, {N. P.} and Bermeshev, {M. V.} and Vezo, {O. S.} and Chapala, {P. P.} and Il'yasova, {Yu. V.}",
year = "2018",
month = mar,
doi = "10.1134/S0965545X18020050",
language = "Английский",
volume = "60",
pages = "162--171",
journal = "Polymer Science - Series A",
issn = "0965-545X",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents

AU - Yevlampieva, N. P.

AU - Bermeshev, M. V.

AU - Vezo, O. S.

AU - Chapala, P. P.

AU - Il'yasova, Yu. V.

PY - 2018/3

Y1 - 2018/3

N2 - The molecular properties of the additive poly(bis(trimethylsilyl)tricyclononene) with the vicinal position of two side groups Si(CH3)(3) in the monomer unit are studied for the first time, and its conformational and kinetic properties are compared with those of the isomer with the geminal position of the same groups. Using the methods of static/dynamic light scattering and viscometry for the samples of the vicinal isomer, the hydrodynamic parameters of molecules are determined and their molecular mass dependences in toluene are ascertained. In addition, the Kuhn segment length of this isomer is estimated. The kinetic rigidity of vicinal and geminal isomers is evaluated by H-1 NMR relaxation from the mobility of protons in Si(CH3)(3) groups. The reasons behind different gas permeabilities of the films based on the polymers with the vicinal and geminal positions of Si(CH3)3 side groups in the monomer unit are discussed.

AB - The molecular properties of the additive poly(bis(trimethylsilyl)tricyclononene) with the vicinal position of two side groups Si(CH3)(3) in the monomer unit are studied for the first time, and its conformational and kinetic properties are compared with those of the isomer with the geminal position of the same groups. Using the methods of static/dynamic light scattering and viscometry for the samples of the vicinal isomer, the hydrodynamic parameters of molecules are determined and their molecular mass dependences in toluene are ascertained. In addition, the Kuhn segment length of this isomer is estimated. The kinetic rigidity of vicinal and geminal isomers is evaluated by H-1 NMR relaxation from the mobility of protons in Si(CH3)(3) groups. The reasons behind different gas permeabilities of the films based on the polymers with the vicinal and geminal positions of Si(CH3)3 side groups in the monomer unit are discussed.

KW - TRICYCLONONENES

KW - QUADRICYCLANE

KW - SEPARATION

KW - POLYMERS

KW - RIGIDITY

U2 - 10.1134/S0965545X18020050

DO - 10.1134/S0965545X18020050

M3 - статья

VL - 60

SP - 162

EP - 171

JO - Polymer Science - Series A

JF - Polymer Science - Series A

SN - 0965-545X

IS - 2

ER -

ID: 37251815