Standard

Molecular inorganic polymers : Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3. / Markovski, Mishel R.; Siidra, Oleg I.; Charkin, Dmitri O.; Nazarchuk, Evgeny V.; Grishaev, Vasili Yu.

In: Zeitschrift fur Kristallographie - Crystalline Materials, Vol. 235, No. 11, 01.11.2020, p. 553-557.

Research output: Contribution to journal › Article › peer-review

Harvard

Markovski, MR, Siidra, OI, Charkin, DO, Nazarchuk, EV & Grishaev, VY 2020, 'Molecular inorganic polymers: Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3', Zeitschrift fur Kristallographie - Crystalline Materials, vol. 235, no. 11, pp. 553-557. https://doi.org/10.1515/zkri-2020-0062

APA

Markovski, M. R., Siidra, O. I., Charkin, D. O., Nazarchuk, E. V., & Grishaev, V. Y. (2020). Molecular inorganic polymers: Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3. Zeitschrift fur Kristallographie - Crystalline Materials, 235(11), 553-557. https://doi.org/10.1515/zkri-2020-0062

Vancouver

Markovski MR, Siidra OI, Charkin DO, Nazarchuk EV, Grishaev VY. Molecular inorganic polymers: Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3. Zeitschrift fur Kristallographie - Crystalline Materials. 2020 Nov 1;235(11):553-557. https://doi.org/10.1515/zkri-2020-0062

Author

Markovski, Mishel R. ; Siidra, Oleg I. ; Charkin, Dmitri O. ; Nazarchuk, Evgeny V. ; Grishaev, Vasili Yu. / Molecular inorganic polymers : Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3. In: Zeitschrift fur Kristallographie - Crystalline Materials. 2020 ; Vol. 235, No. 11. pp. 553-557.

BibTeX

@article{686f7418ece54ba8838e3169c47b3197,
title = "Molecular inorganic polymers: Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3",
abstract = "KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic (P2/n and P2 1/c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- A nd hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date. ",
keywords = "halides, molecular inorganic polymers, selenious acid, selenite",
author = "Markovski, {Mishel R.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Nazarchuk, {Evgeny V.} and Grishaev, {Vasili Yu}",
note = "Funding Information: O.I.S. thanks SPbSU for internal grant COLLAB2019_1 # 38376641. Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged. Funding Information: Research funding: This study was supported by internal grant of SPbSU COLLAB2019_1 # 38376641.",
year = "2020",
month = nov,
day = "1",
doi = "10.1515/zkri-2020-0062",
language = "English",
volume = "235",
pages = "553--557",
journal = "Zeitschrift fur Kristallographie - Crystalline Materials",
issn = "2194-4946",
publisher = "De Gruyter",
number = "11",

}

RIS

TY - JOUR

T1 - Molecular inorganic polymers

T2 - Synthesis and crystal structures of KCl72H 2SeO 3and CsCl7H 2SeO 3

AU - Markovski, Mishel R.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Nazarchuk, Evgeny V.

AU - Grishaev, Vasili Yu

N1 - Funding Information: O.I.S. thanks SPbSU for internal grant COLLAB2019_1 # 38376641. Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged. Funding Information: Research funding: This study was supported by internal grant of SPbSU COLLAB2019_1 # 38376641.

PY - 2020/11/1

Y1 - 2020/11/1

N2 - KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic (P2/n and P2 1/c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- A nd hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date.

AB - KCl72H 2SeO 3 and CsCl7H 2SeO 3 have been synthesized using solution evaporation methods from aqueous solution. Both compounds are monoclinic (P2/n and P2 1/c) and demonstrate new structure types. One symmetrically unique SeO(OH) 2 molecule is present in each structure. SeO(OH) 2 molecules via strong hydrogen bonds form chains in KCl72H 2SeO 3 and layers in ?sCl7H 2SeO 3. The structures of KCl72H 2SeO 3 and CsCl7H 2SeO 3 can be described as consisting of ionic KCl chains and CsCl layers incorporated into the covalent- A nd hydrogen-bonded H 2SeO 3 matrix. To the best of our knowledge, the cases when selenious acid acts as a contributor to the molecular building blocks of salt-inclusion structures are not known to date.

KW - halides

KW - molecular inorganic polymers

KW - selenious acid

KW - selenite

UR - http://www.scopus.com/inward/record.url?scp=85092739695&partnerID=8YFLogxK

U2 - 10.1515/zkri-2020-0062

DO - 10.1515/zkri-2020-0062

M3 - Article

AN - SCOPUS:85092739695

VL - 235

SP - 553

EP - 557

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

IS - 11

ER -

ID: 70546354