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Modulation of luminescence properties for [cyclometalated]-PtII(isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes. / Katkova, Svetlana A.; Luzyanin, Konstantin V.; Novikov, Alexander S.; Kinzhalov, Mikhail A.

In: New Journal of Chemistry, Vol. 45, No. 6, 14.02.2021, p. 2948-2952.

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@article{618e738a8da54898bf41a16f855ed654,
title = "Modulation of luminescence properties for [cyclometalated]-PtII(isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes",
abstract = "Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo- and iodosubstituted perfluorinated arenes to give 1 : 1 adducts. X-FArenes in these co-crystals act as both σh and πh donors forming co-operative C-X⋯Cl-Pt XBs and πh⋯dz2[PtII] contacts. The solid-state photophysical study revealed up to a 2-fold luminescence quantum yield increase upon co-crystallisation due to the formation of these co-operative noncovalent interactions.",
author = "Katkova, {Svetlana A.} and Luzyanin, {Konstantin V.} and Novikov, {Alexander S.} and Kinzhalov, {Mikhail A.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.",
year = "2021",
month = feb,
day = "14",
doi = "10.1039/d0nj05457g",
language = "English",
volume = "45",
pages = "2948--2952",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "6",

}

RIS

TY - JOUR

T1 - Modulation of luminescence properties for [cyclometalated]-PtII(isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes

AU - Katkova, Svetlana A.

AU - Luzyanin, Konstantin V.

AU - Novikov, Alexander S.

AU - Kinzhalov, Mikhail A.

N1 - Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.

PY - 2021/2/14

Y1 - 2021/2/14

N2 - Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo- and iodosubstituted perfluorinated arenes to give 1 : 1 adducts. X-FArenes in these co-crystals act as both σh and πh donors forming co-operative C-X⋯Cl-Pt XBs and πh⋯dz2[PtII] contacts. The solid-state photophysical study revealed up to a 2-fold luminescence quantum yield increase upon co-crystallisation due to the formation of these co-operative noncovalent interactions.

AB - Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo- and iodosubstituted perfluorinated arenes to give 1 : 1 adducts. X-FArenes in these co-crystals act as both σh and πh donors forming co-operative C-X⋯Cl-Pt XBs and πh⋯dz2[PtII] contacts. The solid-state photophysical study revealed up to a 2-fold luminescence quantum yield increase upon co-crystallisation due to the formation of these co-operative noncovalent interactions.

UR - http://www.scopus.com/inward/record.url?scp=85101480346&partnerID=8YFLogxK

U2 - 10.1039/d0nj05457g

DO - 10.1039/d0nj05457g

M3 - Article

AN - SCOPUS:85101480346

VL - 45

SP - 2948

EP - 2952

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 6

ER -

ID: 85582972