Research output: Contribution to journal › Article › peer-review
Modulation of luminescence properties for [cyclometalated]-PtII(isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes. / Katkova, Svetlana A.; Luzyanin, Konstantin V.; Novikov, Alexander S.; Kinzhalov, Mikhail A.
In: New Journal of Chemistry, Vol. 45, No. 6, 14.02.2021, p. 2948-2952.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Modulation of luminescence properties for [cyclometalated]-PtII(isocyanide) complexes upon co-crystallisation with halosubstituted perfluorinated arenes
AU - Katkova, Svetlana A.
AU - Luzyanin, Konstantin V.
AU - Novikov, Alexander S.
AU - Kinzhalov, Mikhail A.
N1 - Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.
PY - 2021/2/14
Y1 - 2021/2/14
N2 - Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo- and iodosubstituted perfluorinated arenes to give 1 : 1 adducts. X-FArenes in these co-crystals act as both σh and πh donors forming co-operative C-X⋯Cl-Pt XBs and πh⋯dz2[PtII] contacts. The solid-state photophysical study revealed up to a 2-fold luminescence quantum yield increase upon co-crystallisation due to the formation of these co-operative noncovalent interactions.
AB - Phosphorescent PtII-based cyclometalated complexes co-crystallise with bromo- and iodosubstituted perfluorinated arenes to give 1 : 1 adducts. X-FArenes in these co-crystals act as both σh and πh donors forming co-operative C-X⋯Cl-Pt XBs and πh⋯dz2[PtII] contacts. The solid-state photophysical study revealed up to a 2-fold luminescence quantum yield increase upon co-crystallisation due to the formation of these co-operative noncovalent interactions.
UR - http://www.scopus.com/inward/record.url?scp=85101480346&partnerID=8YFLogxK
U2 - 10.1039/d0nj05457g
DO - 10.1039/d0nj05457g
M3 - Article
AN - SCOPUS:85101480346
VL - 45
SP - 2948
EP - 2952
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 6
ER -
ID: 85582972