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Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands. / Bulychev, V. P.; Kolomiitsova, T. D.; Shchepkin, D. N.

In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Vol. 76, No. 5, 01.05.1994, p. 647-654.

Research output: Contribution to journal › Article › peer-review

Harvard

Bulychev, VP, Kolomiitsova, TD & Shchepkin, DN 1994, 'Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands', Optics and Spectroscopy (English translation of Optika i Spektroskopiya), vol. 76, no. 5, pp. 647-654.

APA

Bulychev, V. P., Kolomiitsova, T. D., & Shchepkin, D. N. (1994). Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands. Optics and Spectroscopy (English translation of Optika i Spektroskopiya), 76(5), 647-654.

Vancouver

Bulychev VP, Kolomiitsova TD, Shchepkin DN. Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands. Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 1994 May 1;76(5):647-654.

Author

Bulychev, V. P. ; Kolomiitsova, T. D. ; Shchepkin, D. N. / Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands. In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 1994 ; Vol. 76, No. 5. pp. 647-654.

BibTeX

@article{7445737e35bb4a74bc99d9cc2693e838,
title = "Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands",
abstract = "The inhomogeneous mechanism of band shape formation is considered for XH vibrational modes of hydrogen bonded complexes (AD-H...B. Experimentally observed bands are shown to result from superposition of separate bands corresponding to hot, with respect to low-frequency intermolecular vibrations, transitions. Spectral band shapes are substantially influenced by Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of diverse spectral manifestations of Fermi resonance are predicted (a hole at the internal mode frequency, the appearance of an intense narrow band, intensity redistribution between separate parts of a contour, etc), and their dependence are examined on magnitudes and signs of matrix elements determining unperturbed band intensities, as well as on the matrix element of an anharmonic part of the Hamiltonian.",
author = "Bulychev, {V. P.} and Kolomiitsova, {T. D.} and Shchepkin, {D. N.}",
year = "1994",
month = may,
day = "1",
language = "English",
volume = "76",
pages = "647--654",
journal = "OPTICS AND SPECTROSCOPY",
issn = "0030-400X",
publisher = "Pleiades Publishing",
number = "5",

}

RIS

TY - JOUR

T1 - Modeling of the evans holes in inhomogeneously broadened absorption and Raman scattering bands

AU - Bulychev, V. P.

AU - Kolomiitsova, T. D.

AU - Shchepkin, D. N.

PY - 1994/5/1

Y1 - 1994/5/1

N2 - The inhomogeneous mechanism of band shape formation is considered for XH vibrational modes of hydrogen bonded complexes (AD-H...B. Experimentally observed bands are shown to result from superposition of separate bands corresponding to hot, with respect to low-frequency intermolecular vibrations, transitions. Spectral band shapes are substantially influenced by Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of diverse spectral manifestations of Fermi resonance are predicted (a hole at the internal mode frequency, the appearance of an intense narrow band, intensity redistribution between separate parts of a contour, etc), and their dependence are examined on magnitudes and signs of matrix elements determining unperturbed band intensities, as well as on the matrix element of an anharmonic part of the Hamiltonian.

AB - The inhomogeneous mechanism of band shape formation is considered for XH vibrational modes of hydrogen bonded complexes (AD-H...B. Experimentally observed bands are shown to result from superposition of separate bands corresponding to hot, with respect to low-frequency intermolecular vibrations, transitions. Spectral band shapes are substantially influenced by Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of Fermi resonance between terms of the XH modes and internal vibrations of a proton donor. A number of diverse spectral manifestations of Fermi resonance are predicted (a hole at the internal mode frequency, the appearance of an intense narrow band, intensity redistribution between separate parts of a contour, etc), and their dependence are examined on magnitudes and signs of matrix elements determining unperturbed band intensities, as well as on the matrix element of an anharmonic part of the Hamiltonian.

UR - http://www.scopus.com/inward/record.url?scp=0028427314&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0028427314

VL - 76

SP - 647

EP - 654

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 5

ER -

ID: 108591998