Mobility of mesogenic side-chains in liquid crystalline polymers based on the Baylis-Hillman reaction

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Mobility of mesogenic side-chains in liquid crystalline polymers based on the Baylis-Hillman reaction. / Lacey, David; Hall, Alan W.; Lavrenko, Peter N.; Yevlampieva, Natalia P.; Okatova, Olga V.; Polushin, Sergei G.

In: Macromolecular Chemistry and Physics, Vol. 200, No. 5, 01.01.1999, p. 1222-1231.

Research output: Contribution to journal › Article › peer-review

Author

Lacey, David ; Hall, Alan W. ; Lavrenko, Peter N. ; Yevlampieva, Natalia P. ; Okatova, Olga V. ; Polushin, Sergei G. / Mobility of mesogenic side-chains in liquid crystalline polymers based on the Baylis-Hillman reaction. In: Macromolecular Chemistry and Physics. 1999 ; Vol. 200, No. 5. pp. 1222-1231.

BibTeX

@article{42ca592708f348e9acb83dca91b314e6,

title = "Mobility of mesogenic side-chains in liquid crystalline polymers based on the Baylis-Hillman reaction",

abstract = "The hydrodynamic and electro-optical (Kerr effect) properties of two side-chain liquid crystalline (SCLC) polymers have been investigated in benzene and chloroform solution. The polymers are unique in structure and have been prepared using the Baylis-Hillman methodology. The polymers contain (a) a polar group (CN or COCH3) along the polymer backbone and (b) a hydroxyl group on the spacer group which is adjacent to the point of attachment of the spacer/mesogenic side groups to the polymer backbone. Molecular dimensions and the Kerr constants were determined for two SCLC polymers and for three low molar mass materials, the n-alkoxycyanobiphenyls (nOCB), which are structurally similar to the side chain used in the SCLC polymers. These results are discussed in relation to the chemical structure and dipole moment of the monomer unit. Dielectric and electro-optical properties of the SCLC polymer containing the -CN group along the polymer backbone were found to be similar to the properties of the nOCB compounds. The difference in the mesogenic side-chain mobility of the polymers was related to the dipole-dipole interactions of the polar groups along the polymer backbone. {\textcopyright} Wiley-VCH Verlag GmbH, 1999.",

author = "David Lacey and Hall, {Alan W.} and Lavrenko, {Peter N.} and Yevlampieva, {Natalia P.} and Okatova, {Olga V.} and Polushin, {Sergei G.}",

year = "1999",

month = jan,

day = "1",

doi = "10.1002/(sici)1521-3935(19990501)200:5<1222::aid-macp1222>3.0.co;2-w",

language = "English",

volume = "200",

pages = "1222--1231",

journal = "Macromolecular Chemistry and Physics",

issn = "1022-1352",

publisher = "Wiley-Blackwell",

number = "5",

}

RIS

TY - JOUR

T1 - Mobility of mesogenic side-chains in liquid crystalline polymers based on the Baylis-Hillman reaction

AU - Lacey, David

AU - Hall, Alan W.

AU - Lavrenko, Peter N.

AU - Yevlampieva, Natalia P.

AU - Okatova, Olga V.

AU - Polushin, Sergei G.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - The hydrodynamic and electro-optical (Kerr effect) properties of two side-chain liquid crystalline (SCLC) polymers have been investigated in benzene and chloroform solution. The polymers are unique in structure and have been prepared using the Baylis-Hillman methodology. The polymers contain (a) a polar group (CN or COCH3) along the polymer backbone and (b) a hydroxyl group on the spacer group which is adjacent to the point of attachment of the spacer/mesogenic side groups to the polymer backbone. Molecular dimensions and the Kerr constants were determined for two SCLC polymers and for three low molar mass materials, the n-alkoxycyanobiphenyls (nOCB), which are structurally similar to the side chain used in the SCLC polymers. These results are discussed in relation to the chemical structure and dipole moment of the monomer unit. Dielectric and electro-optical properties of the SCLC polymer containing the -CN group along the polymer backbone were found to be similar to the properties of the nOCB compounds. The difference in the mesogenic side-chain mobility of the polymers was related to the dipole-dipole interactions of the polar groups along the polymer backbone. © Wiley-VCH Verlag GmbH, 1999.

AB - The hydrodynamic and electro-optical (Kerr effect) properties of two side-chain liquid crystalline (SCLC) polymers have been investigated in benzene and chloroform solution. The polymers are unique in structure and have been prepared using the Baylis-Hillman methodology. The polymers contain (a) a polar group (CN or COCH3) along the polymer backbone and (b) a hydroxyl group on the spacer group which is adjacent to the point of attachment of the spacer/mesogenic side groups to the polymer backbone. Molecular dimensions and the Kerr constants were determined for two SCLC polymers and for three low molar mass materials, the n-alkoxycyanobiphenyls (nOCB), which are structurally similar to the side chain used in the SCLC polymers. These results are discussed in relation to the chemical structure and dipole moment of the monomer unit. Dielectric and electro-optical properties of the SCLC polymer containing the -CN group along the polymer backbone were found to be similar to the properties of the nOCB compounds. The difference in the mesogenic side-chain mobility of the polymers was related to the dipole-dipole interactions of the polar groups along the polymer backbone. © Wiley-VCH Verlag GmbH, 1999.

UR - http://www.scopus.com/inward/record.url?scp=0000320946&partnerID=8YFLogxK

U2 - 10.1002/(sici)1521-3935(19990501)200:5<1222::aid-macp1222>3.0.co;2-w

DO - 10.1002/(sici)1521-3935(19990501)200:5<1222::aid-macp1222>3.0.co;2-w

M3 - Article

AN - SCOPUS:0000320946

VL - 200

SP - 1222

EP - 1231

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1022-1352

IS - 5

ER -

ID: 103050575