Research output: Contribution to journal › Article
Mixing of the D0+u and δ2u ion-pair states of iodine molecule. / Baturo, V. V.; Lukashov, S. S.; Poretsky, S. A.; Pravilov, A. M.; Vasyutinskii, O. S.
In: Chemical Physics Letters, Vol. 638, 2015, p. 244-248.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Mixing of the D0+u and δ2u ion-pair states of iodine molecule
AU - Baturo, V. V.
AU - Lukashov, S. S.
AU - Poretsky, S. A.
AU - Pravilov, A. M.
AU - Vasyutinskii, O. S.
PY - 2015
Y1 - 2015
N2 - Optical population of the I2(δ2u) state by three-step laser excitation from the ground state View the MathML source via the valence View the MathML source and View the MathML source(bb) states correlating with the I(2P3/2) + I(2P1/2) and the I(2P1/2) + I(2P1/2) dissociation limits, respectively, has been observed for the first time. It has been shown that luminescence from the I2(δ2u) state becomes observable due to interaction between the rovibronic levels of the View the MathML source and δ2u states caused by the nonadiabatic operator Vn describing the heterogeneous interaction taken in the second order of the perturbation theory where the main intermediate state contribution is provided by the γ1u state.
AB - Optical population of the I2(δ2u) state by three-step laser excitation from the ground state View the MathML source via the valence View the MathML source and View the MathML source(bb) states correlating with the I(2P3/2) + I(2P1/2) and the I(2P1/2) + I(2P1/2) dissociation limits, respectively, has been observed for the first time. It has been shown that luminescence from the I2(δ2u) state becomes observable due to interaction between the rovibronic levels of the View the MathML source and δ2u states caused by the nonadiabatic operator Vn describing the heterogeneous interaction taken in the second order of the perturbation theory where the main intermediate state contribution is provided by the γ1u state.
U2 - 10.1016/j.cplett.2015.08.047
DO - 10.1016/j.cplett.2015.08.047
M3 - Article
VL - 638
SP - 244
EP - 248
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
ER -
ID: 4021413