Microextraction-Chromatographic Determination of Furan Derivatives in Transformer Oil

Standard

Microextraction-Chromatographic Determination of Furan Derivatives in Transformer Oil. / Годунов, Павел Анатольевич ; Шишов, Андрей Юрьевич ; Булатов, Андрей Васильевич.

In: Journal of Analytical Chemistry, Vol. 79, No. 12, 01.12.2024, p. 1800–1807.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{f3b30c17074f418b93d319944a2da6c5,

title = "Microextraction-Chromatographic Determination of Furan Derivatives in Transformer Oil",

abstract = "Abstract: A rapid and an environmentally friendly method is developed for the microextraction of furan derivatives from transformer oil for their determination by high-performance liquid chromatography with ultraviolet spectrophotometric detection. Various hydrophilic eutectic solvents were studied as extractants to implement vortex-assisted dispersive liquid–liquid microextraction. The results indicate that a three-component eutectic solvent composed of choline chloride, acetic acid, and water achieves the highest recoveries, ranging from 85 to 96%. The rapid spontaneous phase separation eliminated the need in centrifugation. Limits of detection (3σ) were achieved between 1 and 5 µg/L.",

keywords = "dispersive liquid–liquid microextraction, eutectic solvents, furan derivatives, liquid chromatography, transformer oil",

author = "Годунов, {Павел Анатольевич} and Шишов, {Андрей Юрьевич} and Булатов, {Андрей Васильевич}",

year = "2024",

month = dec,

day = "1",

doi = "10.1134/S1061934824701375",

language = "English",

volume = "79",

pages = "1800–1807",

journal = "Journal of Analytical Chemistry",

issn = "1061-9348",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "12",

}

RIS

TY - JOUR

T1 - Microextraction-Chromatographic Determination of Furan Derivatives in Transformer Oil

AU - Годунов, Павел Анатольевич

AU - Шишов, Андрей Юрьевич

AU - Булатов, Андрей Васильевич

PY - 2024/12/1

Y1 - 2024/12/1

N2 - Abstract: A rapid and an environmentally friendly method is developed for the microextraction of furan derivatives from transformer oil for their determination by high-performance liquid chromatography with ultraviolet spectrophotometric detection. Various hydrophilic eutectic solvents were studied as extractants to implement vortex-assisted dispersive liquid–liquid microextraction. The results indicate that a three-component eutectic solvent composed of choline chloride, acetic acid, and water achieves the highest recoveries, ranging from 85 to 96%. The rapid spontaneous phase separation eliminated the need in centrifugation. Limits of detection (3σ) were achieved between 1 and 5 µg/L.

AB - Abstract: A rapid and an environmentally friendly method is developed for the microextraction of furan derivatives from transformer oil for their determination by high-performance liquid chromatography with ultraviolet spectrophotometric detection. Various hydrophilic eutectic solvents were studied as extractants to implement vortex-assisted dispersive liquid–liquid microextraction. The results indicate that a three-component eutectic solvent composed of choline chloride, acetic acid, and water achieves the highest recoveries, ranging from 85 to 96%. The rapid spontaneous phase separation eliminated the need in centrifugation. Limits of detection (3σ) were achieved between 1 and 5 µg/L.

KW - dispersive liquid–liquid microextraction

KW - eutectic solvents

KW - furan derivatives

KW - liquid chromatography

KW - transformer oil

UR - https://www.mendeley.com/catalogue/df510204-60d3-361e-ae3e-10ab94e91e56/

U2 - 10.1134/S1061934824701375

DO - 10.1134/S1061934824701375

M3 - Article

VL - 79

SP - 1800

EP - 1807

JO - Journal of Analytical Chemistry

JF - Journal of Analytical Chemistry

SN - 1061-9348

IS - 12

ER -

ID: 126982512