Methyl methacrylate polymerization in the presence of C60 (C70) and molecular characteristics of fullerene-containing poly(methyl methacrylate)

Standard

Methyl methacrylate polymerization in the presence of C₆₀ (C₇₀) and molecular characteristics of fullerene-containing poly(methyl methacrylate). / Lopatin, M. A.; Evlampieva, N. P.; Lopatina, T. I.; Kuznetsova, Yu L.; Lavrenko, P. N.

In: Russian Journal of General Chemistry, Vol. 78, No. 8, 08.2008, p. 1545-1552.

Research output: Contribution to journal › Article › peer-review

Author

Lopatin, M. A. ; Evlampieva, N. P. ; Lopatina, T. I. ; Kuznetsova, Yu L. ; Lavrenko, P. N. / Methyl methacrylate polymerization in the presence of C₆₀ (C₇₀) and molecular characteristics of fullerene-containing poly(methyl methacrylate). In: Russian Journal of General Chemistry. 2008 ; Vol. 78, No. 8. pp. 1545-1552.

BibTeX

@article{d02340350d0148e59a72f751b5d93e4d,

title = "Methyl methacrylate polymerization in the presence of C60 (C70) and molecular characteristics of fullerene-containing poly(methyl methacrylate)",

abstract = "Kinetics was studied of bulk polymerization of methyl methacrylate initiated by dicyclohexyl peroxydicarbonate in the presence of tri-n-butylborane and fullerene C60 (or C70) at variable ratio initiator: fullerene. The deceleration of the polymerization in the first stage of the reaction (below 10% conversion) was established by dilatometric method that depended on the fullerene concentration and the mode of its addition to the monomer. It was shown that at similar ratios initiator: fullerene the C 60 inhibited the polymerization process considerably stronger than C70. The gel-permeation chromatography revealed the widening of the molecular weight distribution of the poly(methyl methacrylates) containing C60 or C70 compared to its analog synthesized under the same conditions without fullerene. It was established that in the fullerene-containing poly(methyl methacrylates) all the framework nanospecies are linked by covalent bonds and are mostly accumulated in the low-molecular fractions. The effect of the covalently bound fullerene on the molecular characteristics of polymers were investigated by translational isothermal diffusion, high-speed sedimentation, and viscometry",

author = "Lopatin, {M. A.} and Evlampieva, {N. P.} and Lopatina, {T. I.} and Kuznetsova, {Yu L.} and Lavrenko, {P. N.}",

year = "2008",

month = aug,

doi = "10.1134/S1070363208080136",

language = "English",

volume = "78",

pages = "1545--1552",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "8",

}

RIS

TY - JOUR

T1 - Methyl methacrylate polymerization in the presence of C60 (C70) and molecular characteristics of fullerene-containing poly(methyl methacrylate)

AU - Lopatin, M. A.

AU - Evlampieva, N. P.

AU - Lopatina, T. I.

AU - Kuznetsova, Yu L.

AU - Lavrenko, P. N.

PY - 2008/8

Y1 - 2008/8

N2 - Kinetics was studied of bulk polymerization of methyl methacrylate initiated by dicyclohexyl peroxydicarbonate in the presence of tri-n-butylborane and fullerene C60 (or C70) at variable ratio initiator: fullerene. The deceleration of the polymerization in the first stage of the reaction (below 10% conversion) was established by dilatometric method that depended on the fullerene concentration and the mode of its addition to the monomer. It was shown that at similar ratios initiator: fullerene the C 60 inhibited the polymerization process considerably stronger than C70. The gel-permeation chromatography revealed the widening of the molecular weight distribution of the poly(methyl methacrylates) containing C60 or C70 compared to its analog synthesized under the same conditions without fullerene. It was established that in the fullerene-containing poly(methyl methacrylates) all the framework nanospecies are linked by covalent bonds and are mostly accumulated in the low-molecular fractions. The effect of the covalently bound fullerene on the molecular characteristics of polymers were investigated by translational isothermal diffusion, high-speed sedimentation, and viscometry

AB - Kinetics was studied of bulk polymerization of methyl methacrylate initiated by dicyclohexyl peroxydicarbonate in the presence of tri-n-butylborane and fullerene C60 (or C70) at variable ratio initiator: fullerene. The deceleration of the polymerization in the first stage of the reaction (below 10% conversion) was established by dilatometric method that depended on the fullerene concentration and the mode of its addition to the monomer. It was shown that at similar ratios initiator: fullerene the C 60 inhibited the polymerization process considerably stronger than C70. The gel-permeation chromatography revealed the widening of the molecular weight distribution of the poly(methyl methacrylates) containing C60 or C70 compared to its analog synthesized under the same conditions without fullerene. It was established that in the fullerene-containing poly(methyl methacrylates) all the framework nanospecies are linked by covalent bonds and are mostly accumulated in the low-molecular fractions. The effect of the covalently bound fullerene on the molecular characteristics of polymers were investigated by translational isothermal diffusion, high-speed sedimentation, and viscometry

UR - http://www.scopus.com/inward/record.url?scp=64249120316&partnerID=8YFLogxK

U2 - 10.1134/S1070363208080136

DO - 10.1134/S1070363208080136

M3 - Article

AN - SCOPUS:64249120316

VL - 78

SP - 1545

EP - 1552

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 8

ER -

ID: 72112629