Metathesis-type poly-exo-tricyclononenes with fluoroorganic side substituents

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Metathesis-type poly-exo-tricyclononenes with fluoroorganic side substituents : Synthesis and gas-transport properties. / Karpov, G. O.; Bermeshev, M. V.; Borisov, I. L.; Sterlin, S. R.; Tyutyunov, A. A.; Yevlampieva, N. P.; Bulgakov, B. A.; Volkov, V. V.; Finkelshtein, E. Sh.

In: Polymer, Vol. 153, 26.09.2018, p. 626-636.

Research output: Contribution to journal › Article › peer-review

Author

Karpov, G. O. ; Bermeshev, M. V. ; Borisov, I. L. ; Sterlin, S. R. ; Tyutyunov, A. A. ; Yevlampieva, N. P. ; Bulgakov, B. A. ; Volkov, V. V. ; Finkelshtein, E. Sh. / Metathesis-type poly-exo-tricyclononenes with fluoroorganic side substituents : Synthesis and gas-transport properties. In: Polymer. 2018 ; Vol. 153. pp. 626-636.

BibTeX

@article{1fdc7407c1154f6aa8739ef84fd61e27,

title = "Metathesis-type poly-exo-tricyclononenes with fluoroorganic side substituents: Synthesis and gas-transport properties",

abstract = "The synthesis and gas-transport properties of new metathesis-type polynorbornenes bearing fluoroorganic side groups are reported. The necessary monomers, fluorosubstituted exo-norbornene derivatives (exo-tricyclononenes), were obtained using one-step method based on stereo-and regioselective [2 + 2 + 2]-cycloaddition of quadricyclane and fluoroalkenes. A set of high molecular weight polymers with different side groups were prepared from the synthesized F-substituted exo-tricyclononenes over the 1-st generation Grubbs catalyst. Permeability and diffusion coefficients of various gases (He, H-2, O-2, N-2, CO2, CH4) in these poly-exo-tricyclononenes were determined for the first time and new relationships between polymer structure and gas permeability were established. Metathesis poly-exo-tricyclononene bearing four CF3-groups in each monomer unit displayed the highest gas permeability for the tested gases among metathesis polynorbornenes with F-organic substituents reported so far.",

keywords = "Tricyclononene, Metathesis, Polynorbornene, Polytricyclononene, Membrane gas separation, High performance polymer membranes, POLYNORBORNENE DICARBOXIMIDES, MEMBRANE MATERIALS, QUADRICYCLANE, POLYMERIZATION, CYCLOADDITION, SEPARATION, PERMEABILITY, MOIETIES, LIQUID, NM",

author = "Karpov, {G. O.} and Bermeshev, {M. V.} and Borisov, {I. L.} and Sterlin, {S. R.} and Tyutyunov, {A. A.} and Yevlampieva, {N. P.} and Bulgakov, {B. A.} and Volkov, {V. V.} and Finkelshtein, {E. Sh}",

year = "2018",

month = sep,

day = "26",

doi = "10.1016/j.polymer.2018.08.055",

language = "Английский",

volume = "153",

pages = "626--636",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Metathesis-type poly-exo-tricyclononenes with fluoroorganic side substituents

T2 - Synthesis and gas-transport properties

AU - Karpov, G. O.

AU - Bermeshev, M. V.

AU - Borisov, I. L.

AU - Sterlin, S. R.

AU - Tyutyunov, A. A.

AU - Yevlampieva, N. P.

AU - Bulgakov, B. A.

AU - Volkov, V. V.

AU - Finkelshtein, E. Sh

PY - 2018/9/26

Y1 - 2018/9/26

N2 - The synthesis and gas-transport properties of new metathesis-type polynorbornenes bearing fluoroorganic side groups are reported. The necessary monomers, fluorosubstituted exo-norbornene derivatives (exo-tricyclononenes), were obtained using one-step method based on stereo-and regioselective [2 + 2 + 2]-cycloaddition of quadricyclane and fluoroalkenes. A set of high molecular weight polymers with different side groups were prepared from the synthesized F-substituted exo-tricyclononenes over the 1-st generation Grubbs catalyst. Permeability and diffusion coefficients of various gases (He, H-2, O-2, N-2, CO2, CH4) in these poly-exo-tricyclononenes were determined for the first time and new relationships between polymer structure and gas permeability were established. Metathesis poly-exo-tricyclononene bearing four CF3-groups in each monomer unit displayed the highest gas permeability for the tested gases among metathesis polynorbornenes with F-organic substituents reported so far.

AB - The synthesis and gas-transport properties of new metathesis-type polynorbornenes bearing fluoroorganic side groups are reported. The necessary monomers, fluorosubstituted exo-norbornene derivatives (exo-tricyclononenes), were obtained using one-step method based on stereo-and regioselective [2 + 2 + 2]-cycloaddition of quadricyclane and fluoroalkenes. A set of high molecular weight polymers with different side groups were prepared from the synthesized F-substituted exo-tricyclononenes over the 1-st generation Grubbs catalyst. Permeability and diffusion coefficients of various gases (He, H-2, O-2, N-2, CO2, CH4) in these poly-exo-tricyclononenes were determined for the first time and new relationships between polymer structure and gas permeability were established. Metathesis poly-exo-tricyclononene bearing four CF3-groups in each monomer unit displayed the highest gas permeability for the tested gases among metathesis polynorbornenes with F-organic substituents reported so far.

KW - Tricyclononene

KW - Metathesis

KW - Polynorbornene

KW - Polytricyclononene

KW - Membrane gas separation

KW - High performance polymer membranes

KW - POLYNORBORNENE DICARBOXIMIDES

KW - MEMBRANE MATERIALS

KW - QUADRICYCLANE

KW - POLYMERIZATION

KW - CYCLOADDITION

KW - SEPARATION

KW - PERMEABILITY

KW - MOIETIES

KW - LIQUID

KW - NM

U2 - 10.1016/j.polymer.2018.08.055

DO - 10.1016/j.polymer.2018.08.055

M3 - статья

VL - 153

SP - 626

EP - 636

JO - Polymer

JF - Polymer

SN - 0032-3861

ER -

ID: 37251495