The mechanism of formation of the perovskite-like layered structure of the oxide Gd2SrFe2O7 was studied. The limiting stages are those of formation of phases with perovskite (GdFeO3, SrFeO3-x ) and K2NiF4 (GdSrFeO4) structures. The Mössbauer study has shown that iron atoms exist in a heterovalent state (Fe3+ and Fe4+) only in the structure of SrFeO3-x ).

Original languageEnglish
Pages (from-to)973-978
Number of pages6
JournalRussian Journal of General Chemistry
Volume77
Issue number6
DOIs
StatePublished - Jun 2007

    Scopus subject areas

  • Chemistry(all)

ID: 87428148