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Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction. / Zhuzhel'Skii, D. V.; Krylova, V. A.; Ivanov, V. D.; Malev, V. V.

In: Russian Journal of Electrochemistry, Vol. 45, No. 2, 01.02.2009, p. 145-151.

Research output: Contribution to journal › Article › peer-review

Harvard

Zhuzhel'Skii, DV, Krylova, VA, Ivanov, VD & Malev, VV 2009, 'Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction', Russian Journal of Electrochemistry, vol. 45, no. 2, pp. 145-151. https://doi.org/10.1134/S1023193509020049

APA

Zhuzhel'Skii, D. V., Krylova, V. A., Ivanov, V. D., & Malev, V. V. (2009). Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction. Russian Journal of Electrochemistry, 45(2), 145-151. https://doi.org/10.1134/S1023193509020049

Vancouver

Zhuzhel'Skii DV, Krylova VA, Ivanov VD, Malev VV. Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction. Russian Journal of Electrochemistry. 2009 Feb 1;45(2):145-151. https://doi.org/10.1134/S1023193509020049

Author

Zhuzhel'Skii, D. V. ; Krylova, V. A. ; Ivanov, V. D. ; Malev, V. V. / Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction. In: Russian Journal of Electrochemistry. 2009 ; Vol. 45, No. 2. pp. 145-151.

BibTeX

@article{79020b62f16249c58c5f95bd80f27c3e,
title = "Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction",
abstract = "Polyaniline films (further, CPANI) were obtained under the conditions of oxygen cathodic reduction in the aniline-containing solution on the electrodes of mixed indium tin oxide (ITO), graphite, and gold. CPANI films are characterized by redox processes in the potential ranges of 0.1-0.2 V and 0.4 V (SCE). These processes are caused by the polymer chain fragments of different structure and the ratio between the peaks corresponding to these processes varies significantly as dependent on the synthesis conditions (electrode material, stirring, etc). The mechanism of electrode processes on CPANI is studied using the methods of cyclic voltammetry and quartz microgravimetry. It is found that only hydrogen cations and supporting electrolyte anions participate in the electrode process at the potentials of 0.1-0.2 V. The mechanism of redox processes on the obtained polymer films is discussed.",
keywords = "Cyclic voltammetry, Electrochemical microgravimetry, Modified electrodes, Poly-o-aminophenol, Polyaniline",
author = "Zhuzhel'Skii, {D. V.} and Krylova, {V. A.} and Ivanov, {V. D.} and Malev, {V. V.}",
year = "2009",
month = feb,
day = "1",
doi = "10.1134/S1023193509020049",
language = "English",
volume = "45",
pages = "145--151",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Mechanism of electrochemical reactions of polyaniline films formed under the conditions of cathodic oxygen reduction

AU - Zhuzhel'Skii, D. V.

AU - Krylova, V. A.

AU - Ivanov, V. D.

AU - Malev, V. V.

PY - 2009/2/1

Y1 - 2009/2/1

N2 - Polyaniline films (further, CPANI) were obtained under the conditions of oxygen cathodic reduction in the aniline-containing solution on the electrodes of mixed indium tin oxide (ITO), graphite, and gold. CPANI films are characterized by redox processes in the potential ranges of 0.1-0.2 V and 0.4 V (SCE). These processes are caused by the polymer chain fragments of different structure and the ratio between the peaks corresponding to these processes varies significantly as dependent on the synthesis conditions (electrode material, stirring, etc). The mechanism of electrode processes on CPANI is studied using the methods of cyclic voltammetry and quartz microgravimetry. It is found that only hydrogen cations and supporting electrolyte anions participate in the electrode process at the potentials of 0.1-0.2 V. The mechanism of redox processes on the obtained polymer films is discussed.

AB - Polyaniline films (further, CPANI) were obtained under the conditions of oxygen cathodic reduction in the aniline-containing solution on the electrodes of mixed indium tin oxide (ITO), graphite, and gold. CPANI films are characterized by redox processes in the potential ranges of 0.1-0.2 V and 0.4 V (SCE). These processes are caused by the polymer chain fragments of different structure and the ratio between the peaks corresponding to these processes varies significantly as dependent on the synthesis conditions (electrode material, stirring, etc). The mechanism of electrode processes on CPANI is studied using the methods of cyclic voltammetry and quartz microgravimetry. It is found that only hydrogen cations and supporting electrolyte anions participate in the electrode process at the potentials of 0.1-0.2 V. The mechanism of redox processes on the obtained polymer films is discussed.

KW - Cyclic voltammetry

KW - Electrochemical microgravimetry

KW - Modified electrodes

KW - Poly-o-aminophenol

KW - Polyaniline

UR - http://www.scopus.com/inward/record.url?scp=62249152448&partnerID=8YFLogxK

U2 - 10.1134/S1023193509020049

DO - 10.1134/S1023193509020049

M3 - Article

AN - SCOPUS:62249152448

VL - 45

SP - 145

EP - 151

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 2

ER -

ID: 43006728