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Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions. / Shulevich, Yu V.; Zakharova, Yu A.; Tolstoi, P. M.; Vovk, M. A.; Dukhanina, E. G.; Bykov, D. S.; Navrotskii, A. V.; Novakov, I. A.

In: Polymer Science - Series B, Vol. 61, No. 6, 01.11.2019, p. 715-724.

Research output: Contribution to journal › Article › peer-review

Harvard

Shulevich, YV, Zakharova, YA, Tolstoi, PM, Vovk, MA, Dukhanina, EG, Bykov, DS, Navrotskii, AV & Novakov, IA 2019, 'Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions', Polymer Science - Series B, vol. 61, no. 6, pp. 715-724. https://doi.org/10.1134/S1560090419060125

APA

Shulevich, Y. V., Zakharova, Y. A., Tolstoi, P. M., Vovk, M. A., Dukhanina, E. G., Bykov, D. S., Navrotskii, A. V., & Novakov, I. A. (2019). Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions. Polymer Science - Series B, 61(6), 715-724. https://doi.org/10.1134/S1560090419060125

Vancouver

Shulevich YV, Zakharova YA, Tolstoi PM, Vovk MA, Dukhanina EG, Bykov DS et al. Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions. Polymer Science - Series B. 2019 Nov 1;61(6):715-724. https://doi.org/10.1134/S1560090419060125

Author

Shulevich, Yu V. ; Zakharova, Yu A. ; Tolstoi, P. M. ; Vovk, M. A. ; Dukhanina, E. G. ; Bykov, D. S. ; Navrotskii, A. V. ; Novakov, I. A. / Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions. In: Polymer Science - Series B. 2019 ; Vol. 61, No. 6. pp. 715-724.

BibTeX

@article{d8c452ff039f4d5d82dcbaf4bd84ba0b,
title = "Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions",
abstract = "Abstract: The kinetic features of the radical polymerization of trimethylmethacryloyloxyethylammonium methyl sulfate in micellar solutions of an oppositely charged surfactant—sodium dodecyl sulfate—are studied by NMR spectroscopy. It is shown that matrix polymerization occurs by the zip mechanism only in dilute surfactant solutions containing spherical micelles at a molar ratio of [monomer]/[surfactant] ≤ 1 and at a significant increase in the polymerization rate. An increase in surfactant concentration leads to a change in the mechanism of matrix polymerization accompanied by a decrease in the rate of polymerization, which is probably related to a change in the shape of micelles. The molecular weight of the obtained polyelectrolytes depends on the molar ratio of the components and is minimal at the [monomer]/[surfactant] equimolar ratio.",
author = "Shulevich, {Yu V.} and Zakharova, {Yu A.} and Tolstoi, {P. M.} and Vovk, {M. A.} and Dukhanina, {E. G.} and Bykov, {D. S.} and Navrotskii, {A. V.} and Novakov, {I. A.}",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",
year = "2019",
month = nov,
day = "1",
doi = "10.1134/S1560090419060125",
language = "English",
volume = "61",
pages = "715--724",
journal = "Polymer Science - Series B",
issn = "1560-0904",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Matrix Polymerization of Trimethylmetacryloyloxyethylethylammonium Methyl Sulfate in Sodium Dodecyl Sulfate Micellar Solutions

AU - Shulevich, Yu V.

AU - Zakharova, Yu A.

AU - Tolstoi, P. M.

AU - Vovk, M. A.

AU - Dukhanina, E. G.

AU - Bykov, D. S.

AU - Navrotskii, A. V.

AU - Novakov, I. A.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Abstract: The kinetic features of the radical polymerization of trimethylmethacryloyloxyethylammonium methyl sulfate in micellar solutions of an oppositely charged surfactant—sodium dodecyl sulfate—are studied by NMR spectroscopy. It is shown that matrix polymerization occurs by the zip mechanism only in dilute surfactant solutions containing spherical micelles at a molar ratio of [monomer]/[surfactant] ≤ 1 and at a significant increase in the polymerization rate. An increase in surfactant concentration leads to a change in the mechanism of matrix polymerization accompanied by a decrease in the rate of polymerization, which is probably related to a change in the shape of micelles. The molecular weight of the obtained polyelectrolytes depends on the molar ratio of the components and is minimal at the [monomer]/[surfactant] equimolar ratio.

AB - Abstract: The kinetic features of the radical polymerization of trimethylmethacryloyloxyethylammonium methyl sulfate in micellar solutions of an oppositely charged surfactant—sodium dodecyl sulfate—are studied by NMR spectroscopy. It is shown that matrix polymerization occurs by the zip mechanism only in dilute surfactant solutions containing spherical micelles at a molar ratio of [monomer]/[surfactant] ≤ 1 and at a significant increase in the polymerization rate. An increase in surfactant concentration leads to a change in the mechanism of matrix polymerization accompanied by a decrease in the rate of polymerization, which is probably related to a change in the shape of micelles. The molecular weight of the obtained polyelectrolytes depends on the molar ratio of the components and is minimal at the [monomer]/[surfactant] equimolar ratio.

UR - http://www.scopus.com/inward/record.url?scp=85078465910&partnerID=8YFLogxK

U2 - 10.1134/S1560090419060125

DO - 10.1134/S1560090419060125

M3 - Article

AN - SCOPUS:85078465910

VL - 61

SP - 715

EP - 724

JO - Polymer Science - Series B

JF - Polymer Science - Series B

SN - 1560-0904

IS - 6

ER -

ID: 86294129