Research output: Contribution to journal › Article
Mass spectrometric study of thermodynamic properties of gaseous tin borates SnB2O4 and Sn2B2O5. / Shugurov, S.M.; Lopatin, S.I.; Panin, A.I.; Emelyanova, K.A.
In: International Journal of Mass Spectrometry, Vol. 392, 2015, p. 69-72.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Mass spectrometric study of thermodynamic properties of gaseous tin borates SnB2O4 and Sn2B2O5
AU - Shugurov, S.M.
AU - Lopatin, S.I.
AU - Panin, A.I.
AU - Emelyanova, K.A.
PY - 2015
Y1 - 2015
N2 - © 2015 Elsevier B.V. All rights reserved.The formation and stability of the gaseous oxyacid salts SnB2O4 and Sn2B2O5 were studied. The gaseous SnB2O4 and Sn2B2O5 were identified in the gas phase over the SnO2-B2O3 system in the temperature range 1320-1500 K. Determination of m/z-values, isotopic patterns and appearance energies of all gaseous species was performed by means of high-temperature mass spectrometry. Thermodynamic data for the gaseous SnB2O4 and Sn2B2O5 molecules were obtained by means Knudsen effusion mass spectrometry and quantum chemistry DFT M06 and MP2 calculations.
AB - © 2015 Elsevier B.V. All rights reserved.The formation and stability of the gaseous oxyacid salts SnB2O4 and Sn2B2O5 were studied. The gaseous SnB2O4 and Sn2B2O5 were identified in the gas phase over the SnO2-B2O3 system in the temperature range 1320-1500 K. Determination of m/z-values, isotopic patterns and appearance energies of all gaseous species was performed by means of high-temperature mass spectrometry. Thermodynamic data for the gaseous SnB2O4 and Sn2B2O5 molecules were obtained by means Knudsen effusion mass spectrometry and quantum chemistry DFT M06 and MP2 calculations.
U2 - 10.1016/j.ijms.2015.09.007
DO - 10.1016/j.ijms.2015.09.007
M3 - Article
VL - 392
SP - 69
EP - 72
JO - International Journal of Mass Spectrometry
JF - International Journal of Mass Spectrometry
SN - 1387-3806
ER -
ID: 3980054