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Martensitic phase transformation and shape memory properties of the as-cast NiCuTiHf and NiCuTiHfZr alloys. / Baradari, Sadjad; Resnina, Natalia; Belyaev, Sergey; Nili-Ahmadabadi, Mahmoud.

In: Journal of Alloys and Compounds, Vol. 888, 161534, 25.12.2021.

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Baradari, Sadjad ; Resnina, Natalia ; Belyaev, Sergey ; Nili-Ahmadabadi, Mahmoud. / Martensitic phase transformation and shape memory properties of the as-cast NiCuTiHf and NiCuTiHfZr alloys. In: Journal of Alloys and Compounds. 2021 ; Vol. 888.

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@article{f8ce0e4cf74342a68d8a8843cccd44ef,
title = "Martensitic phase transformation and shape memory properties of the as-cast NiCuTiHf and NiCuTiHfZr alloys",
abstract = "This study investigates the structure, martensitic phase transformation behavior, and shape memory properties of the quaternary Ni44.8Cu5Ti45.2Hf5 and quinary Ni44.8Cu5Ti40.2Hf5Zr5 and Ni45.5Cu5Ti39.5Hf5Zr5 shape memory alloys (SMAs) in the as-cast state. The alloys exhibited a dual-phase microstructure com-posed of matrix phase (austenite or martensite depending on the chemical composition) and Ti2Ni-type phase. The experimental results revealed that the alloys underwent a one-step B2 -> B19' transformation. The Ni44.8Cu5Ti45.2Hf5 alloy showed a maximum shape memory strain of 6.2% with a recovery ratio of 81% upon thermal cycling under a tensile stress of 300 MPa, while in the Ni44.8Cu5Ti40.2Hf5Zr5 alloy, a maximum shape memory strain of about 5% was obtained under 500 MPa with a recovery ratio of 86%. The as-cast Ni44.8Cu5Ti45.2Hf5 alloy showed superelastic response with 0.3% maximum transformation strain at 125 degrees C. On the other hand, the Ni44.8Cu5Ti45.2Hf5 alloy showed the best superelastic response at 65 degrees C with a recoverable strain of about 1.9%. Two-way shape memory strains of 0.8% and 3.3% were obtained in the Ni44.8Cu5Ti45.2Hf5 and Ni44.8Cu5Ti40.2Hf5Zr5 alloys, respectively. The Ni45.5Cu5Ti39.5Hf5Zr5 alloy, however, did not reveal the shape memory effect. Results obtained from low-temperature X-ray diffraction (XRD) analysis indicated that the B2 -> B19' transformation was considerably suppressed in this alloy and the volume fraction of B19' martensite did not exceed 8% even at an ultra-low temperature of - 150 degrees C. (C) 2021 Elsevier B.V. All rights reserved.",
keywords = "Martensitic phase transformation, Shape memory alloys (SMAs), Shape memory strain, Superelasticity, Two-way shape memory effect, MECHANICAL-PROPERTIES, CYCLIC REVERSIBILITY, WIDE HYSTERESIS, TEMPERATURES, ZR, COLD, MICROSTRUCTURE, BEHAVIORS, HF",
author = "Sadjad Baradari and Natalia Resnina and Sergey Belyaev and Mahmoud Nili-Ahmadabadi",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",
year = "2021",
month = dec,
day = "25",
doi = "10.1016/j.jallcom.2021.161534",
language = "English",
volume = "888",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Martensitic phase transformation and shape memory properties of the as-cast NiCuTiHf and NiCuTiHfZr alloys

AU - Baradari, Sadjad

AU - Resnina, Natalia

AU - Belyaev, Sergey

AU - Nili-Ahmadabadi, Mahmoud

N1 - Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/12/25

Y1 - 2021/12/25

N2 - This study investigates the structure, martensitic phase transformation behavior, and shape memory properties of the quaternary Ni44.8Cu5Ti45.2Hf5 and quinary Ni44.8Cu5Ti40.2Hf5Zr5 and Ni45.5Cu5Ti39.5Hf5Zr5 shape memory alloys (SMAs) in the as-cast state. The alloys exhibited a dual-phase microstructure com-posed of matrix phase (austenite or martensite depending on the chemical composition) and Ti2Ni-type phase. The experimental results revealed that the alloys underwent a one-step B2 -> B19' transformation. The Ni44.8Cu5Ti45.2Hf5 alloy showed a maximum shape memory strain of 6.2% with a recovery ratio of 81% upon thermal cycling under a tensile stress of 300 MPa, while in the Ni44.8Cu5Ti40.2Hf5Zr5 alloy, a maximum shape memory strain of about 5% was obtained under 500 MPa with a recovery ratio of 86%. The as-cast Ni44.8Cu5Ti45.2Hf5 alloy showed superelastic response with 0.3% maximum transformation strain at 125 degrees C. On the other hand, the Ni44.8Cu5Ti45.2Hf5 alloy showed the best superelastic response at 65 degrees C with a recoverable strain of about 1.9%. Two-way shape memory strains of 0.8% and 3.3% were obtained in the Ni44.8Cu5Ti45.2Hf5 and Ni44.8Cu5Ti40.2Hf5Zr5 alloys, respectively. The Ni45.5Cu5Ti39.5Hf5Zr5 alloy, however, did not reveal the shape memory effect. Results obtained from low-temperature X-ray diffraction (XRD) analysis indicated that the B2 -> B19' transformation was considerably suppressed in this alloy and the volume fraction of B19' martensite did not exceed 8% even at an ultra-low temperature of - 150 degrees C. (C) 2021 Elsevier B.V. All rights reserved.

AB - This study investigates the structure, martensitic phase transformation behavior, and shape memory properties of the quaternary Ni44.8Cu5Ti45.2Hf5 and quinary Ni44.8Cu5Ti40.2Hf5Zr5 and Ni45.5Cu5Ti39.5Hf5Zr5 shape memory alloys (SMAs) in the as-cast state. The alloys exhibited a dual-phase microstructure com-posed of matrix phase (austenite or martensite depending on the chemical composition) and Ti2Ni-type phase. The experimental results revealed that the alloys underwent a one-step B2 -> B19' transformation. The Ni44.8Cu5Ti45.2Hf5 alloy showed a maximum shape memory strain of 6.2% with a recovery ratio of 81% upon thermal cycling under a tensile stress of 300 MPa, while in the Ni44.8Cu5Ti40.2Hf5Zr5 alloy, a maximum shape memory strain of about 5% was obtained under 500 MPa with a recovery ratio of 86%. The as-cast Ni44.8Cu5Ti45.2Hf5 alloy showed superelastic response with 0.3% maximum transformation strain at 125 degrees C. On the other hand, the Ni44.8Cu5Ti45.2Hf5 alloy showed the best superelastic response at 65 degrees C with a recoverable strain of about 1.9%. Two-way shape memory strains of 0.8% and 3.3% were obtained in the Ni44.8Cu5Ti45.2Hf5 and Ni44.8Cu5Ti40.2Hf5Zr5 alloys, respectively. The Ni45.5Cu5Ti39.5Hf5Zr5 alloy, however, did not reveal the shape memory effect. Results obtained from low-temperature X-ray diffraction (XRD) analysis indicated that the B2 -> B19' transformation was considerably suppressed in this alloy and the volume fraction of B19' martensite did not exceed 8% even at an ultra-low temperature of - 150 degrees C. (C) 2021 Elsevier B.V. All rights reserved.

KW - Martensitic phase transformation

KW - Shape memory alloys (SMAs)

KW - Shape memory strain

KW - Superelasticity

KW - Two-way shape memory effect

KW - MECHANICAL-PROPERTIES

KW - CYCLIC REVERSIBILITY

KW - WIDE HYSTERESIS

KW - TEMPERATURES

KW - ZR

KW - COLD

KW - MICROSTRUCTURE

KW - BEHAVIORS

KW - HF

UR - http://www.scopus.com/inward/record.url?scp=85112774853&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2021.161534

DO - 10.1016/j.jallcom.2021.161534

M3 - Article

AN - SCOPUS:85112774853

VL - 888

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

M1 - 161534

ER -

ID: 85050071