Standard

Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides. / Колесников, Илья Евгеньевич; Enikeeva, Kamila ; Litvinov, I. A.; Islamov, Daut R.; Khrizanforova, Vera V.; Budnikova, Yu. H.; Lyubina, Anna P.; Voloshina, Alexandra D.; Musina, E.I.; Karasik, Andrey A.

In: Inorganica Chimica Acta, Vol. 571, 122211, 01.10.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Колесников, ИЕ, Enikeeva, K, Litvinov, IA, Islamov, DR, Khrizanforova, VV, Budnikova, YH, Lyubina, AP, Voloshina, AD, Musina, EI & Karasik, AA 2024, 'Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides', Inorganica Chimica Acta, vol. 571, 122211. https://doi.org/10.1016/j.ica.2024.122211

APA

Колесников, И. Е., Enikeeva, K., Litvinov, I. A., Islamov, D. R., Khrizanforova, V. V., Budnikova, Y. H., Lyubina, A. P., Voloshina, A. D., Musina, E. I., & Karasik, A. A. (2024). Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides. Inorganica Chimica Acta, 571, [122211]. https://doi.org/10.1016/j.ica.2024.122211

Vancouver

Колесников ИЕ, Enikeeva K, Litvinov IA, Islamov DR, Khrizanforova VV, Budnikova YH et al. Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides. Inorganica Chimica Acta. 2024 Oct 1;571. 122211. https://doi.org/10.1016/j.ica.2024.122211

Author

Колесников, Илья Евгеньевич ; Enikeeva, Kamila ; Litvinov, I. A. ; Islamov, Daut R. ; Khrizanforova, Vera V. ; Budnikova, Yu. H. ; Lyubina, Anna P. ; Voloshina, Alexandra D. ; Musina, E.I. ; Karasik, Andrey A. / Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides. In: Inorganica Chimica Acta. 2024 ; Vol. 571.

BibTeX

@article{634e8149389547c9ab6ee22e95ac1a30,
title = "Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides",
abstract = "New N,O-hybrid ligands with methylene fragment between coordinating nitrogen and oxygen donor centers namely, dialkyl(pyridine-2-ylmethyl)phosphine oxides and dialkyl(quinoline-2-ylmethyl)phosphine oxides were synthesized. During complexation with MnCl2 pyridyl-containing dialkylphosphine oxides act as chelating N,O-bidentate ligands, while quinoline-containing dialkylphosphine oxide acts as O-monodentate ligand. All compounds were structurally characterized by mass-spectrometry, IR spectroscopy, elemental analysis, the monocrystal and powder X-ray analyses. The photoluminescence, electrochemical properties and cytotoxicity of the synthesized compounds were studied. It was found that obtained ligands and their manganese(II) complexes exhibit green–blue and blue-violet luminescence. High catalytic activity of manganese(II) complex with diisopropyl(pyridine-2-ylmethyl)phosphine oxide in HER (hydrogen evolution reaction) was found. Manganese(II) complexes based on pyridyl-containing phosphine oxides demonstrate high cytotoxic activity towards HuTu80 cancer cell line.",
keywords = "Cytotoxicity, Electrochemistry, Luminescence, MnII complexes, N,O-chelating ligands, Pyridyl-containing phosphine oxides, Quinoline-containing phosphine oxides, Tertiary phosphine oxides, X-ray structure",
author = "Колесников, {Илья Евгеньевич} and Kamila Enikeeva and Litvinov, {I. A.} and Islamov, {Daut R.} and Khrizanforova, {Vera V.} and Budnikova, {Yu. H.} and Lyubina, {Anna P.} and Voloshina, {Alexandra D.} and E.I. Musina and Karasik, {Andrey A.}",
year = "2024",
month = oct,
day = "1",
doi = "10.1016/j.ica.2024.122211",
language = "русский",
volume = "571",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Manganese(II) complexes based on pyridyl- and quinolyl-containing dialkylphosphine oxides

AU - Колесников, Илья Евгеньевич

AU - Enikeeva, Kamila

AU - Litvinov, I. A.

AU - Islamov, Daut R.

AU - Khrizanforova, Vera V.

AU - Budnikova, Yu. H.

AU - Lyubina, Anna P.

AU - Voloshina, Alexandra D.

AU - Musina, E.I.

AU - Karasik, Andrey A.

PY - 2024/10/1

Y1 - 2024/10/1

N2 - New N,O-hybrid ligands with methylene fragment between coordinating nitrogen and oxygen donor centers namely, dialkyl(pyridine-2-ylmethyl)phosphine oxides and dialkyl(quinoline-2-ylmethyl)phosphine oxides were synthesized. During complexation with MnCl2 pyridyl-containing dialkylphosphine oxides act as chelating N,O-bidentate ligands, while quinoline-containing dialkylphosphine oxide acts as O-monodentate ligand. All compounds were structurally characterized by mass-spectrometry, IR spectroscopy, elemental analysis, the monocrystal and powder X-ray analyses. The photoluminescence, electrochemical properties and cytotoxicity of the synthesized compounds were studied. It was found that obtained ligands and their manganese(II) complexes exhibit green–blue and blue-violet luminescence. High catalytic activity of manganese(II) complex with diisopropyl(pyridine-2-ylmethyl)phosphine oxide in HER (hydrogen evolution reaction) was found. Manganese(II) complexes based on pyridyl-containing phosphine oxides demonstrate high cytotoxic activity towards HuTu80 cancer cell line.

AB - New N,O-hybrid ligands with methylene fragment between coordinating nitrogen and oxygen donor centers namely, dialkyl(pyridine-2-ylmethyl)phosphine oxides and dialkyl(quinoline-2-ylmethyl)phosphine oxides were synthesized. During complexation with MnCl2 pyridyl-containing dialkylphosphine oxides act as chelating N,O-bidentate ligands, while quinoline-containing dialkylphosphine oxide acts as O-monodentate ligand. All compounds were structurally characterized by mass-spectrometry, IR spectroscopy, elemental analysis, the monocrystal and powder X-ray analyses. The photoluminescence, electrochemical properties and cytotoxicity of the synthesized compounds were studied. It was found that obtained ligands and their manganese(II) complexes exhibit green–blue and blue-violet luminescence. High catalytic activity of manganese(II) complex with diisopropyl(pyridine-2-ylmethyl)phosphine oxide in HER (hydrogen evolution reaction) was found. Manganese(II) complexes based on pyridyl-containing phosphine oxides demonstrate high cytotoxic activity towards HuTu80 cancer cell line.

KW - Cytotoxicity

KW - Electrochemistry

KW - Luminescence

KW - MnII complexes

KW - N,O-chelating ligands

KW - Pyridyl-containing phosphine oxides

KW - Quinoline-containing phosphine oxides

KW - Tertiary phosphine oxides

KW - X-ray structure

UR - https://www.mendeley.com/catalogue/c166750e-f931-3389-990c-49def8a496c9/

U2 - 10.1016/j.ica.2024.122211

DO - 10.1016/j.ica.2024.122211

M3 - статья

VL - 571

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 122211

ER -

ID: 121188276