Research output: Contribution to journal › Conference article › peer-review
Magnetic properties of iron nanoparticles in mesoporous silica matrix. / Grigorieva, N. A.; Grigoriev, S. V.; Eckerlebe, H.; Eliseev, A. A.; Napolskii, K. S.; Lukashin, A. V.; Tretyakov, Yu D.
In: Journal of Magnetism and Magnetic Materials, Vol. 300, No. 1, 05.2006, p. e342-e345.Research output: Contribution to journal › Conference article › peer-review
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TY - JOUR
T1 - Magnetic properties of iron nanoparticles in mesoporous silica matrix
AU - Grigorieva, N. A.
AU - Grigoriev, S. V.
AU - Eckerlebe, H.
AU - Eliseev, A. A.
AU - Napolskii, K. S.
AU - Lukashin, A. V.
AU - Tretyakov, Yu D.
PY - 2006/5
Y1 - 2006/5
N2 - Anisotropic iron nanoparticles were successfully synthesized within the pores of mesoporous silica matrix by intercalation of hydrophobic iron complex (Fe(CO)5) into the hydrophobic part of the mesoporous silica-surfactant composite. It was shown that the particles are uniform and well ordered in the matrix and their shape and size are in good agreement with that of the pores. The samples demonstrate spin-glass-like behavior at low temperatures, which transforms to the superparamagnetic one with temperature increases. Nanoscale-related magnetic properties were investigated by polarized SANS. It was shown that hysteretic and the spin-glass-like behavior may be attributed to bunches of the iron nanowires with average radius of 4.7 nm.
AB - Anisotropic iron nanoparticles were successfully synthesized within the pores of mesoporous silica matrix by intercalation of hydrophobic iron complex (Fe(CO)5) into the hydrophobic part of the mesoporous silica-surfactant composite. It was shown that the particles are uniform and well ordered in the matrix and their shape and size are in good agreement with that of the pores. The samples demonstrate spin-glass-like behavior at low temperatures, which transforms to the superparamagnetic one with temperature increases. Nanoscale-related magnetic properties were investigated by polarized SANS. It was shown that hysteretic and the spin-glass-like behavior may be attributed to bunches of the iron nanowires with average radius of 4.7 nm.
KW - Magnetic nanowires
KW - Mesoporous silica
KW - Nanoreactors
KW - SAPNS
UR - http://www.scopus.com/inward/record.url?scp=33644657029&partnerID=8YFLogxK
U2 - 10.1016/j.jmmm.2005.10.116
DO - 10.1016/j.jmmm.2005.10.116
M3 - Conference article
AN - SCOPUS:33644657029
VL - 300
SP - e342-e345
JO - Journal of Magnetism and Magnetic Materials
JF - Journal of Magnetism and Magnetic Materials
SN - 0304-8853
IS - 1
T2 - Third International Symposium on Magnetism 2005
Y2 - 26 June 2005 through 30 June 2005
ER -
ID: 86431939