Standard

Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters. / Volkov, Sergey; Yukhno, Valentina; Banaru, Alexander; Deyneko, Dina; Aksenov, Sergey; Charkin, Dmitri; Povolotskiy, Alexey; Savchenko, Yevgeny; Antonov, Andrey; Krzhizhanovskaya, Maria; Ugolkov, Valery; Firsova, Vera; Vaitieva, Yulia; Boldyrev, Kirill; Bubnova, Rimma.

In: Dalton Transactions, Vol. 53, No. 19, 29.04.2024, p. 8112-8117.

Research output: Contribution to journal › Article › peer-review

Harvard

Volkov, S, Yukhno, V, Banaru, A, Deyneko, D, Aksenov, S, Charkin, D, Povolotskiy, A, Savchenko, Y, Antonov, A, Krzhizhanovskaya, M, Ugolkov, V, Firsova, V, Vaitieva, Y, Boldyrev, K & Bubnova, R 2024, 'Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters', Dalton Transactions, vol. 53, no. 19, pp. 8112-8117. https://doi.org/10.1039/d3dt04048h

APA

Volkov, S., Yukhno, V., Banaru, A., Deyneko, D., Aksenov, S., Charkin, D., Povolotskiy, A., Savchenko, Y., Antonov, A., Krzhizhanovskaya, M., Ugolkov, V., Firsova, V., Vaitieva, Y., Boldyrev, K., & Bubnova, R. (2024). Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters. Dalton Transactions, 53(19), 8112-8117. https://doi.org/10.1039/d3dt04048h

Vancouver

Volkov S, Yukhno V, Banaru A, Deyneko D, Aksenov S, Charkin D et al. Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters. Dalton Transactions. 2024 Apr 29;53(19):8112-8117. https://doi.org/10.1039/d3dt04048h

Author

Volkov, Sergey ; Yukhno, Valentina ; Banaru, Alexander ; Deyneko, Dina ; Aksenov, Sergey ; Charkin, Dmitri ; Povolotskiy, Alexey ; Savchenko, Yevgeny ; Antonov, Andrey ; Krzhizhanovskaya, Maria ; Ugolkov, Valery ; Firsova, Vera ; Vaitieva, Yulia ; Boldyrev, Kirill ; Bubnova, Rimma. / Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters. In: Dalton Transactions. 2024 ; Vol. 53, No. 19. pp. 8112-8117.

BibTeX

@article{7036cf0e124e45f794d6b1340c95beea,
title = "Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters",
abstract = "Solvothermal reaction of magnesium nitrate and boron oxide in N,N-dimethylformamide produced a number of particularly complex supramolecular magnesium borates. Five topologically different types of negatively charged {Mg@[B18φ34-35]}-clusters, φ = O, OH, were observed with the magnesium cation as a core and octadecaborate anions as shells. The clusters assemble via common borate polyhedra forming 1D chains, a 2D mesoporous layer, and 3D mesoporous frameworks with an effective channel width of up to 16 {\AA}. Topological analysis of the clusters in combination with the modular crystallography approach indicates that numerous new functional materials can be obtained by varying their assembly mode. At least one compound containing such clusters exhibits a very strong luminescence.",
author = "Sergey Volkov and Valentina Yukhno and Alexander Banaru and Dina Deyneko and Sergey Aksenov and Dmitri Charkin and Alexey Povolotskiy and Yevgeny Savchenko and Andrey Antonov and Maria Krzhizhanovskaya and Valery Ugolkov and Vera Firsova and Yulia Vaitieva and Kirill Boldyrev and Rimma Bubnova",
year = "2024",
month = apr,
day = "29",
doi = "10.1039/d3dt04048h",
language = "English",
volume = "53",
pages = "8112--8117",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "19",

}

RIS

TY - JOUR

T1 - Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B 18 φ 34–35 ]}-clusters

AU - Volkov, Sergey

AU - Yukhno, Valentina

AU - Banaru, Alexander

AU - Deyneko, Dina

AU - Aksenov, Sergey

AU - Charkin, Dmitri

AU - Povolotskiy, Alexey

AU - Savchenko, Yevgeny

AU - Antonov, Andrey

AU - Krzhizhanovskaya, Maria

AU - Ugolkov, Valery

AU - Firsova, Vera

AU - Vaitieva, Yulia

AU - Boldyrev, Kirill

AU - Bubnova, Rimma

PY - 2024/4/29

Y1 - 2024/4/29

N2 - Solvothermal reaction of magnesium nitrate and boron oxide in N,N-dimethylformamide produced a number of particularly complex supramolecular magnesium borates. Five topologically different types of negatively charged {Mg@[B18φ34-35]}-clusters, φ = O, OH, were observed with the magnesium cation as a core and octadecaborate anions as shells. The clusters assemble via common borate polyhedra forming 1D chains, a 2D mesoporous layer, and 3D mesoporous frameworks with an effective channel width of up to 16 Å. Topological analysis of the clusters in combination with the modular crystallography approach indicates that numerous new functional materials can be obtained by varying their assembly mode. At least one compound containing such clusters exhibits a very strong luminescence.

AB - Solvothermal reaction of magnesium nitrate and boron oxide in N,N-dimethylformamide produced a number of particularly complex supramolecular magnesium borates. Five topologically different types of negatively charged {Mg@[B18φ34-35]}-clusters, φ = O, OH, were observed with the magnesium cation as a core and octadecaborate anions as shells. The clusters assemble via common borate polyhedra forming 1D chains, a 2D mesoporous layer, and 3D mesoporous frameworks with an effective channel width of up to 16 Å. Topological analysis of the clusters in combination with the modular crystallography approach indicates that numerous new functional materials can be obtained by varying their assembly mode. At least one compound containing such clusters exhibits a very strong luminescence.

UR - https://www.mendeley.com/catalogue/8cfe9488-2311-3b85-bdbf-4ae954d9f12d/

U2 - 10.1039/d3dt04048h

DO - 10.1039/d3dt04048h

M3 - Article

VL - 53

SP - 8112

EP - 8117

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 19

ER -

ID: 121097992