Standard

Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics. / Tsvetkov, N.V.; Lezov, A.A.; Vlasov, P.S.; Gubarev, A.S.; Lezova, A.A.; Lebedeva, E.V.; Polushina, G.E.; Domnina, N.S.

In: Polymer, Vol. 122, 28.07.2017, p. 34–44.

Research output: Contribution to journal › Article › peer-review

Harvard

Tsvetkov, NV, Lezov, AA, Vlasov, PS, Gubarev, AS, Lezova, AA, Lebedeva, EV, Polushina, GE & Domnina, NS 2017, 'Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics', Polymer, vol. 122, pp. 34–44. https://doi.org/10.1016/j.polymer.2017.06.030

APA

Tsvetkov, N. V., Lezov, A. A., Vlasov, P. S., Gubarev, A. S., Lezova, A. A., Lebedeva, E. V., Polushina, G. E., & Domnina, N. S. (2017). Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics. Polymer, 122, 34–44. https://doi.org/10.1016/j.polymer.2017.06.030

Vancouver

Tsvetkov NV, Lezov AA, Vlasov PS, Gubarev AS, Lezova AA, Lebedeva EV et al. Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics. Polymer. 2017 Jul 28;122:34–44. https://doi.org/10.1016/j.polymer.2017.06.030

Author

Tsvetkov, N.V. ; Lezov, A.A. ; Vlasov, P.S. ; Gubarev, A.S. ; Lezova, A.A. ; Lebedeva, E.V. ; Polushina, G.E. ; Domnina, N.S. / Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics. In: Polymer. 2017 ; Vol. 122. pp. 34–44.

BibTeX

@article{3f2c22d884a0415980f8942c968bd996,
title = "Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics",
abstract = "A series of water-soluble poly(carboxybetaines) (poly(4-(diallyl(methyl)ammonio)butanoates), poly(DAMAB)) was synthesized. Detailed studies of the solution properties of these poly(carboxybetaines) were performed using viscometry, static and dynamic light scattering, velocity sedimentation and flow birefringence. Molar masses, other molecular parameters and conformational characteristics of the macromolecules were determined in water and 1 M NaClNaCl solutions. The Mark-Kuhn-Houwink and scaling equations were obtained for poly(DAMAB). It was established that 1 M NaCl solution is a thermodynamically good solvent for poly(DAMAB). In water, the conformation of poly(DAMAB) molecules is similar to that of a polymer coil under θ -conditions. The Kuhn segment length for poly(DAMAB) molecules was A=7nm in water and in 1 M NaCl solution. Data on the thermal stability of DAMAB and its polymer were obtained. Thorough consideration of contributions of optical effects of micro- and macroform into the observed flow biref",
keywords = "Zwitterionic polymer, Conformational characteristics, Reduced viscosity, Carboxybetaine",
author = "N.V. Tsvetkov and A.A. Lezov and P.S. Vlasov and A.S. Gubarev and A.A. Lezova and E.V. Lebedeva and G.E. Polushina and N.S. Domnina",
year = "2017",
month = jul,
day = "28",
doi = "10.1016/j.polymer.2017.06.030",
language = "English",
volume = "122",
pages = "34–44",
journal = "Polymer",
issn = "0032-3861",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Macromolecules of polycarboxybetaine poly(4-N,N-diallyl-N-methylammonio) butanoate: Synthesis and molecular characteristics

AU - Tsvetkov, N.V.

AU - Lezov, A.A.

AU - Vlasov, P.S.

AU - Gubarev, A.S.

AU - Lezova, A.A.

AU - Lebedeva, E.V.

AU - Polushina, G.E.

AU - Domnina, N.S.

PY - 2017/7/28

Y1 - 2017/7/28

N2 - A series of water-soluble poly(carboxybetaines) (poly(4-(diallyl(methyl)ammonio)butanoates), poly(DAMAB)) was synthesized. Detailed studies of the solution properties of these poly(carboxybetaines) were performed using viscometry, static and dynamic light scattering, velocity sedimentation and flow birefringence. Molar masses, other molecular parameters and conformational characteristics of the macromolecules were determined in water and 1 M NaClNaCl solutions. The Mark-Kuhn-Houwink and scaling equations were obtained for poly(DAMAB). It was established that 1 M NaCl solution is a thermodynamically good solvent for poly(DAMAB). In water, the conformation of poly(DAMAB) molecules is similar to that of a polymer coil under θ -conditions. The Kuhn segment length for poly(DAMAB) molecules was A=7nm in water and in 1 M NaCl solution. Data on the thermal stability of DAMAB and its polymer were obtained. Thorough consideration of contributions of optical effects of micro- and macroform into the observed flow biref

AB - A series of water-soluble poly(carboxybetaines) (poly(4-(diallyl(methyl)ammonio)butanoates), poly(DAMAB)) was synthesized. Detailed studies of the solution properties of these poly(carboxybetaines) were performed using viscometry, static and dynamic light scattering, velocity sedimentation and flow birefringence. Molar masses, other molecular parameters and conformational characteristics of the macromolecules were determined in water and 1 M NaClNaCl solutions. The Mark-Kuhn-Houwink and scaling equations were obtained for poly(DAMAB). It was established that 1 M NaCl solution is a thermodynamically good solvent for poly(DAMAB). In water, the conformation of poly(DAMAB) molecules is similar to that of a polymer coil under θ -conditions. The Kuhn segment length for poly(DAMAB) molecules was A=7nm in water and in 1 M NaCl solution. Data on the thermal stability of DAMAB and its polymer were obtained. Thorough consideration of contributions of optical effects of micro- and macroform into the observed flow biref

KW - Zwitterionic polymer

KW - Conformational characteristics

KW - Reduced viscosity

KW - Carboxybetaine

U2 - 10.1016/j.polymer.2017.06.030

DO - 10.1016/j.polymer.2017.06.030

M3 - Article

VL - 122

SP - 34

EP - 44

JO - Polymer

JF - Polymer

SN - 0032-3861

ER -

ID: 7752618