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Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films. / Grishchenko, A. E.; Pavlov, G. M.; Fomin, G. A.; Mikhajlova, N. A.; Ryumtsev, E. I.; Tur, D. R.

In: Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, Vol. 43, No. 12, 2001, p. 2117-2122.

Research output: Contribution to journal › Article › peer-review

Harvard

Grishchenko, AE, Pavlov, GM, Fomin, GA, Mikhajlova, NA, Ryumtsev, EI & Tur, DR 2001, 'Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films', Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, vol. 43, no. 12, pp. 2117-2122.

APA

Grishchenko, A. E., Pavlov, G. M., Fomin, G. A., Mikhajlova, N. A., Ryumtsev, E. I., & Tur, D. R. (2001). Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films. Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 43(12), 2117-2122.

Vancouver

Grishchenko AE, Pavlov GM, Fomin GA, Mikhajlova NA, Ryumtsev EI, Tur DR. Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films. Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya. 2001;43(12):2117-2122.

Author

Grishchenko, A. E. ; Pavlov, G. M. ; Fomin, G. A. ; Mikhajlova, N. A. ; Ryumtsev, E. I. ; Tur, D. R. / Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films. In: Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya. 2001 ; Vol. 43, No. 12. pp. 2117-2122.

BibTeX

@article{43a1982cecd846c0acb5a3dea2c3586c,
title = "Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films",
abstract = "The films of three poly(fluoroalkoxyphosphazenes) were studied by the methods of photoelasticity and incident polarized beam. A difference in the polarizability of P=N bonds was estimated ΔaP=N=20×10-31 m3. A low degree of delocalization in a polyphosphazene chain upon the electron binding of atoms was established. For the polymers studied, the length of the Kuhn segments lies within (40-80)×10-10 m. The thickness of the optically anisotropic surface layers (H0>1.1×10-4 m) and the orientational order parameters (-0.054>S0>-0.5) suggest a high level of ordering of the fragments of polyphosphazene molecules in the surface layers. The polyphosphazene chains are shown to be primarily oriented in parallel to the surfaces of the films.",
author = "Grishchenko, {A. E.} and Pavlov, {G. M.} and Fomin, {G. A.} and Mikhajlova, {N. A.} and Ryumtsev, {E. I.} and Tur, {D. R.}",
year = "2001",
language = "English",
volume = "43",
pages = "2117--2122",
journal = "ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А",
issn = "2308-1120",
publisher = "Издательство {"}Наука{"}",
number = "12",

}

RIS

TY - JOUR

T1 - Macromolecular conformations of poly(fluoroalkoxyphosphazenes) and optical properties of the related films

AU - Grishchenko, A. E.

AU - Pavlov, G. M.

AU - Fomin, G. A.

AU - Mikhajlova, N. A.

AU - Ryumtsev, E. I.

AU - Tur, D. R.

PY - 2001

Y1 - 2001

N2 - The films of three poly(fluoroalkoxyphosphazenes) were studied by the methods of photoelasticity and incident polarized beam. A difference in the polarizability of P=N bonds was estimated ΔaP=N=20×10-31 m3. A low degree of delocalization in a polyphosphazene chain upon the electron binding of atoms was established. For the polymers studied, the length of the Kuhn segments lies within (40-80)×10-10 m. The thickness of the optically anisotropic surface layers (H0>1.1×10-4 m) and the orientational order parameters (-0.054>S0>-0.5) suggest a high level of ordering of the fragments of polyphosphazene molecules in the surface layers. The polyphosphazene chains are shown to be primarily oriented in parallel to the surfaces of the films.

AB - The films of three poly(fluoroalkoxyphosphazenes) were studied by the methods of photoelasticity and incident polarized beam. A difference in the polarizability of P=N bonds was estimated ΔaP=N=20×10-31 m3. A low degree of delocalization in a polyphosphazene chain upon the electron binding of atoms was established. For the polymers studied, the length of the Kuhn segments lies within (40-80)×10-10 m. The thickness of the optically anisotropic surface layers (H0>1.1×10-4 m) and the orientational order parameters (-0.054>S0>-0.5) suggest a high level of ordering of the fragments of polyphosphazene molecules in the surface layers. The polyphosphazene chains are shown to be primarily oriented in parallel to the surfaces of the films.

UR - http://www.scopus.com/inward/record.url?scp=0035550215&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0035550215

VL - 43

SP - 2117

EP - 2122

JO - ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А

JF - ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А

SN - 2308-1120

IS - 12

ER -

ID: 94254888