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Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines. / Galimova, Milyausha F.; Zueva, Ekaterina M.; Dobrynin, Alexey B.; Kolesnikov, Ilya E. ; Musin, Rustem R.; Musina, Elvira I.; Karasik, Andrey A.

In: Dalton Transactions, Vol. 50, No. 38, 2021, p. 13421-13429.

Research output: Contribution to journal › Article › peer-review

Harvard

Galimova, MF, Zueva, EM, Dobrynin, AB, Kolesnikov, IE, Musin, RR, Musina, EI & Karasik, AA 2021, 'Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines', Dalton Transactions, vol. 50, no. 38, pp. 13421-13429.

APA

Galimova, M. F., Zueva, E. M., Dobrynin, A. B., Kolesnikov, I. E., Musin, R. R., Musina, E. I., & Karasik, A. A. (2021). Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines. Dalton Transactions, 50(38), 13421-13429.

Vancouver

Galimova MF, Zueva EM, Dobrynin AB, Kolesnikov IE, Musin RR, Musina EI et al. Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines. Dalton Transactions. 2021;50(38):13421-13429.

Author

Galimova, Milyausha F. ; Zueva, Ekaterina M. ; Dobrynin, Alexey B. ; Kolesnikov, Ilya E. ; Musin, Rustem R. ; Musina, Elvira I. ; Karasik, Andrey A. / Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines. In: Dalton Transactions. 2021 ; Vol. 50, No. 38. pp. 13421-13429.

BibTeX

@article{eace03cdacd94020848a5472c5254dc8,
title = "Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines",
abstract = "Two luminescent Cu4I4-cubane tetramers with N-methyl-10-(p-halogenophenyl)-5,10-dihydrophenarsazine ligands were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. The UV-Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations. The luminescence behavior was found to be rather different from that of recently reported tetranuclear copper iodide cubane clusters based on As,O-analogues - 10-(aryl)phenoxarsines. The crystalline powders of both complexes exhibit the temperature-dependent dual-band emission: the low-energy emission originates from the cluster-centered (3CC) triplet state, whereas the high-energy emission was attributed to the intraligand (3IL) triplet state.",
author = "Galimova, {Milyausha F.} and Zueva, {Ekaterina M.} and Dobrynin, {Alexey B.} and Kolesnikov, {Ilya E.} and Musin, {Rustem R.} and Musina, {Elvira I.} and Karasik, {Andrey A.}",
year = "2021",
language = "English",
volume = "50",
pages = "13421--13429",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines

AU - Galimova, Milyausha F.

AU - Zueva, Ekaterina M.

AU - Dobrynin, Alexey B.

AU - Kolesnikov, Ilya E.

AU - Musin, Rustem R.

AU - Musina, Elvira I.

AU - Karasik, Andrey A.

PY - 2021

Y1 - 2021

N2 - Two luminescent Cu4I4-cubane tetramers with N-methyl-10-(p-halogenophenyl)-5,10-dihydrophenarsazine ligands were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. The UV-Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations. The luminescence behavior was found to be rather different from that of recently reported tetranuclear copper iodide cubane clusters based on As,O-analogues - 10-(aryl)phenoxarsines. The crystalline powders of both complexes exhibit the temperature-dependent dual-band emission: the low-energy emission originates from the cluster-centered (3CC) triplet state, whereas the high-energy emission was attributed to the intraligand (3IL) triplet state.

AB - Two luminescent Cu4I4-cubane tetramers with N-methyl-10-(p-halogenophenyl)-5,10-dihydrophenarsazine ligands were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. The UV-Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations. The luminescence behavior was found to be rather different from that of recently reported tetranuclear copper iodide cubane clusters based on As,O-analogues - 10-(aryl)phenoxarsines. The crystalline powders of both complexes exhibit the temperature-dependent dual-band emission: the low-energy emission originates from the cluster-centered (3CC) triplet state, whereas the high-energy emission was attributed to the intraligand (3IL) triplet state.

UR - https://europepmc.org/article/med/34477191

UR - https://proxy.library.spbu.ru:2369/en/content/articlelanding/2021/DT/D1DT02344F

M3 - Article

VL - 50

SP - 13421

EP - 13429

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 38

ER -

ID: 87270890