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@article{8a4c0f20400847598984c89f7e880aab,
title = "Luminescence of the NeI2 van der Waals complex",
abstract = "The T-shaped NeI 2(E0 g +) van der Waals (vdW) complexes populated in the NeI 2(E,v E = 0–2, n E=0–2 ← B,19,n B = 0 ← X,0,n X = 0) excitation pathway have been studied. Analysis of the luminescence excitation spectra, luminescence spectra themselves and temporal behaviors of the luminescence intensities of the transitions observed has been carried out. The NeI 2(E,v E,n E) luminescence has been discovered. This is the first direct observation of a halogen molecule vdW complex luminescence. It has also been found that lifetime of the NeI 2(E,v E,n E) complex depends on the v E value: it is equal to 8 ns for the NeI 2(E,v E = 0,n E) when vibrational predissociation (VP) is impossible and ≤2 ns when VP channels are open. ",
keywords = "DYNAMICS, EXCITATION, VIBRATIONAL PREDISSOCIATION",
author = "Батуро, {Вера Владимировна} and Лукашов, {Сергей Сергеевич} and Порецкий, {Сергей Артемович} and Правилов, {Анатолий Михайлович}",
note = "Funding Information: The authors acknowledge Russian Foundation for Basic Researches for grant 16-03-00225 .",
year = "2018",
month = mar,
day = "16",
doi = "10.1016/j.cplett.2018.02.031",
language = "English",
volume = "696",
pages = "26--30",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Luminescence of the NeI2 van der Waals complex

AU - Батуро, Вера Владимировна

AU - Лукашов, Сергей Сергеевич

AU - Порецкий, Сергей Артемович

AU - Правилов, Анатолий Михайлович

N1 - Funding Information: The authors acknowledge Russian Foundation for Basic Researches for grant 16-03-00225 .

PY - 2018/3/16

Y1 - 2018/3/16

N2 - The T-shaped NeI 2(E0 g +) van der Waals (vdW) complexes populated in the NeI 2(E,v E = 0–2, n E=0–2 ← B,19,n B = 0 ← X,0,n X = 0) excitation pathway have been studied. Analysis of the luminescence excitation spectra, luminescence spectra themselves and temporal behaviors of the luminescence intensities of the transitions observed has been carried out. The NeI 2(E,v E,n E) luminescence has been discovered. This is the first direct observation of a halogen molecule vdW complex luminescence. It has also been found that lifetime of the NeI 2(E,v E,n E) complex depends on the v E value: it is equal to 8 ns for the NeI 2(E,v E = 0,n E) when vibrational predissociation (VP) is impossible and ≤2 ns when VP channels are open.

AB - The T-shaped NeI 2(E0 g +) van der Waals (vdW) complexes populated in the NeI 2(E,v E = 0–2, n E=0–2 ← B,19,n B = 0 ← X,0,n X = 0) excitation pathway have been studied. Analysis of the luminescence excitation spectra, luminescence spectra themselves and temporal behaviors of the luminescence intensities of the transitions observed has been carried out. The NeI 2(E,v E,n E) luminescence has been discovered. This is the first direct observation of a halogen molecule vdW complex luminescence. It has also been found that lifetime of the NeI 2(E,v E,n E) complex depends on the v E value: it is equal to 8 ns for the NeI 2(E,v E = 0,n E) when vibrational predissociation (VP) is impossible and ≤2 ns when VP channels are open.

KW - DYNAMICS

KW - EXCITATION

KW - VIBRATIONAL PREDISSOCIATION

UR - http://www.scopus.com/inward/record.url?scp=85042281923&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/luminescence-nei2van-der-waals-complex

U2 - 10.1016/j.cplett.2018.02.031

DO - 10.1016/j.cplett.2018.02.031

M3 - Article

VL - 696

SP - 26

EP - 30

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

ER -

ID: 18306366