Luminescence behaviour of Au(i)-Cu(i) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(i) complexes

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Luminescence behaviour of Au(i)-Cu(i) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(i) complexes. / Petrovskii, Stanislav K. ; Paderina, Aleksandra V. ; Sizova, Anastasia A. ; Baranov, Andrey Yu. ; Artem'ev, Alexander A. ; Sizov, Vladimir V. ; Grachova, Elena V. .

In: Dalton Transactions, Vol. 49, No. 38, 14.10.2020, p. 13430-13439.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{504985d899e245319ecc8f09fe83b515,

title = "Luminescence behaviour of Au(i)-Cu(i) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(i) complexes",

abstract = "A set of alkynyl-tris(2-pyridyl)phosphine Au(i) complexes was synthesized and characterized. Free coordination functions on the ligand environment periphery, namely 'scorpionate' PPy3 and the C C bond, allowed these ditopic metalloligands to be selectively linked to 1D coordination polymers by reaction with Cu(i), which used both Cu-(N-PPy3) and Cu-(eta(2)-C C) coordination modes. Single-crystal and powder XRD, NMR, and XPS techniques were used to characterize the coordination polymers obtained. Heterobimetallic Au(I)-Cu(I) coordination polymers demonstrate triplet photoluminescence which was studied by spectroscopic and computational methods to understand the pathway of energy transfer inside the chain of linked chromophore centres. The intriguing feature of the electronic structure of heterobimetallic supramolecular assemblies is the 'long-distance' electronic transition involving PhC2 and PPy3 ligands located at a distance of more than 1 nm from each other. Thus, the assembly of a heterobimetallic coordination polymer from relatively simple 'building blocks' retains the block-wise nature of the electronic structure, but the photophysical properties of the polymer are fundamentally different from the properties of discrete organometallic components.",

keywords = "TRIPODAL LIGANDS, PHOSPHINE, TRIS(2-PYRIDYL)PHOSPHINE, 2-BROMOPYRIDINE, OXIDE, MODULATION, CLUSTERS, MONO",

author = "Petrovskii, {Stanislav K.} and Paderina, {Aleksandra V.} and Sizova, {Anastasia A.} and Baranov, {Andrey Yu.} and Artem'ev, {Alexander A.} and Sizov, {Vladimir V.} and Grachova, {Elena V.}",

year = "2020",

month = oct,

day = "14",

doi = "10.1039/D0DT02583F",

language = "English",

volume = "49",

pages = "13430--13439",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

}

RIS

TY - JOUR

T1 - Luminescence behaviour of Au(i)-Cu(i) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(i) complexes

AU - Petrovskii, Stanislav K.

AU - Paderina, Aleksandra V.

AU - Sizova, Anastasia A.

AU - Baranov, Andrey Yu.

AU - Artem'ev, Alexander A.

AU - Sizov, Vladimir V.

AU - Grachova, Elena V.

PY - 2020/10/14

Y1 - 2020/10/14

N2 - A set of alkynyl-tris(2-pyridyl)phosphine Au(i) complexes was synthesized and characterized. Free coordination functions on the ligand environment periphery, namely 'scorpionate' PPy3 and the C C bond, allowed these ditopic metalloligands to be selectively linked to 1D coordination polymers by reaction with Cu(i), which used both Cu-(N-PPy3) and Cu-(eta(2)-C C) coordination modes. Single-crystal and powder XRD, NMR, and XPS techniques were used to characterize the coordination polymers obtained. Heterobimetallic Au(I)-Cu(I) coordination polymers demonstrate triplet photoluminescence which was studied by spectroscopic and computational methods to understand the pathway of energy transfer inside the chain of linked chromophore centres. The intriguing feature of the electronic structure of heterobimetallic supramolecular assemblies is the 'long-distance' electronic transition involving PhC2 and PPy3 ligands located at a distance of more than 1 nm from each other. Thus, the assembly of a heterobimetallic coordination polymer from relatively simple 'building blocks' retains the block-wise nature of the electronic structure, but the photophysical properties of the polymer are fundamentally different from the properties of discrete organometallic components.

AB - A set of alkynyl-tris(2-pyridyl)phosphine Au(i) complexes was synthesized and characterized. Free coordination functions on the ligand environment periphery, namely 'scorpionate' PPy3 and the C C bond, allowed these ditopic metalloligands to be selectively linked to 1D coordination polymers by reaction with Cu(i), which used both Cu-(N-PPy3) and Cu-(eta(2)-C C) coordination modes. Single-crystal and powder XRD, NMR, and XPS techniques were used to characterize the coordination polymers obtained. Heterobimetallic Au(I)-Cu(I) coordination polymers demonstrate triplet photoluminescence which was studied by spectroscopic and computational methods to understand the pathway of energy transfer inside the chain of linked chromophore centres. The intriguing feature of the electronic structure of heterobimetallic supramolecular assemblies is the 'long-distance' electronic transition involving PhC2 and PPy3 ligands located at a distance of more than 1 nm from each other. Thus, the assembly of a heterobimetallic coordination polymer from relatively simple 'building blocks' retains the block-wise nature of the electronic structure, but the photophysical properties of the polymer are fundamentally different from the properties of discrete organometallic components.

KW - TRIPODAL LIGANDS

KW - PHOSPHINE

KW - TRIS(2-PYRIDYL)PHOSPHINE

KW - 2-BROMOPYRIDINE

KW - OXIDE

KW - MODULATION

KW - CLUSTERS

KW - MONO

UR - http://www.scopus.com/inward/record.url?scp=85092246894&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/ccba2397-77dc-39db-94da-487b59e023b3/

U2 - 10.1039/D0DT02583F

DO - 10.1039/D0DT02583F

M3 - Article

C2 - 32966450

AN - SCOPUS:85092246894

VL - 49

SP - 13430

EP - 13439

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 38

ER -

ID: 62500687