Standard

Low-temperature IR study of ozone interaction with ethylene adsorbed on silica. / Manoilova, O. V.; Lavalley, J. C.; Tsyganenko, N. M.; Tsyganenko, A. A.

In: Langmuir, Vol. 14, No. 20, 29.09.1998, p. 5813-5819.

Research output: Contribution to journal › Article › peer-review

Harvard

Manoilova, OV, Lavalley, JC, Tsyganenko, NM & Tsyganenko, AA 1998, 'Low-temperature IR study of ozone interaction with ethylene adsorbed on silica', Langmuir, vol. 14, no. 20, pp. 5813-5819.

APA

Manoilova, O. V., Lavalley, J. C., Tsyganenko, N. M., & Tsyganenko, A. A. (1998). Low-temperature IR study of ozone interaction with ethylene adsorbed on silica. Langmuir, 14(20), 5813-5819.

Vancouver

Manoilova OV, Lavalley JC, Tsyganenko NM, Tsyganenko AA. Low-temperature IR study of ozone interaction with ethylene adsorbed on silica. Langmuir. 1998 Sep 29;14(20):5813-5819.

Author

Manoilova, O. V. ; Lavalley, J. C. ; Tsyganenko, N. M. ; Tsyganenko, A. A. / Low-temperature IR study of ozone interaction with ethylene adsorbed on silica. In: Langmuir. 1998 ; Vol. 14, No. 20. pp. 5813-5819.

BibTeX

@article{31be84a1231a4364993fabe547eaac39,
title = "Low-temperature IR study of ozone interaction with ethylene adsorbed on silica",
abstract = "The advantages of the adsorbed state for spectral studies of the ozonolysis mechanism are illustrated by ozone reaction with ethylene on silica. The sample with preadsorbed ethylene or C2D4 was brought into contact with 14O3, 18O3, or mixed 16O3/18O3 from the solution in liquid oxygen at 60-77 K or from the gas phase at 77 K. The method enables us to detect the first products of ozonolysis, including primary and secondary ozonides or formaldehyde, arising already at 77K or below and to follow their transformations in a wide temperature interval, not arailable for solid matrices or solutions. Formaldehyde, which should arise at the intermediate step of the reaction, is formed when an excess of ozone is admitted from the gas phase. It is supposed that O3 reaction with dioxymethyl (Criegee intermediate) prevents its recombination with formaldehyde, providing the stabilization of the latter.",
author = "Manoilova, {O. V.} and Lavalley, {J. C.} and Tsyganenko, {N. M.} and Tsyganenko, {A. A.}",
year = "1998",
month = sep,
day = "29",
language = "English",
volume = "14",
pages = "5813--5819",
journal = "Langmuir",
issn = "0743-7463",
publisher = "American Chemical Society",
number = "20",

}

RIS

TY - JOUR

T1 - Low-temperature IR study of ozone interaction with ethylene adsorbed on silica

AU - Manoilova, O. V.

AU - Lavalley, J. C.

AU - Tsyganenko, N. M.

AU - Tsyganenko, A. A.

PY - 1998/9/29

Y1 - 1998/9/29

N2 - The advantages of the adsorbed state for spectral studies of the ozonolysis mechanism are illustrated by ozone reaction with ethylene on silica. The sample with preadsorbed ethylene or C2D4 was brought into contact with 14O3, 18O3, or mixed 16O3/18O3 from the solution in liquid oxygen at 60-77 K or from the gas phase at 77 K. The method enables us to detect the first products of ozonolysis, including primary and secondary ozonides or formaldehyde, arising already at 77K or below and to follow their transformations in a wide temperature interval, not arailable for solid matrices or solutions. Formaldehyde, which should arise at the intermediate step of the reaction, is formed when an excess of ozone is admitted from the gas phase. It is supposed that O3 reaction with dioxymethyl (Criegee intermediate) prevents its recombination with formaldehyde, providing the stabilization of the latter.

AB - The advantages of the adsorbed state for spectral studies of the ozonolysis mechanism are illustrated by ozone reaction with ethylene on silica. The sample with preadsorbed ethylene or C2D4 was brought into contact with 14O3, 18O3, or mixed 16O3/18O3 from the solution in liquid oxygen at 60-77 K or from the gas phase at 77 K. The method enables us to detect the first products of ozonolysis, including primary and secondary ozonides or formaldehyde, arising already at 77K or below and to follow their transformations in a wide temperature interval, not arailable for solid matrices or solutions. Formaldehyde, which should arise at the intermediate step of the reaction, is formed when an excess of ozone is admitted from the gas phase. It is supposed that O3 reaction with dioxymethyl (Criegee intermediate) prevents its recombination with formaldehyde, providing the stabilization of the latter.

UR - http://www.scopus.com/inward/record.url?scp=0032165580&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032165580

VL - 14

SP - 5813

EP - 5819

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 20

ER -

ID: 41683281