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Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition. / Missyul, A.; Kreuzer, M.; Usoltsev, O.; Arsentev, M.; Chislov, M.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 650, No. 16, e202400032, 29.07.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Missyul, A, Kreuzer, M, Usoltsev, O, Arsentev, M & Chislov, M 2024, 'Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 650, no. 16, e202400032. https://doi.org/10.1002/zaac.202400032

APA

Missyul, A., Kreuzer, M., Usoltsev, O., Arsentev, M., & Chislov, M. (2024). Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition. Zeitschrift fur Anorganische und Allgemeine Chemie, 650(16), [e202400032]. https://doi.org/10.1002/zaac.202400032

Vancouver

Missyul A, Kreuzer M, Usoltsev O, Arsentev M, Chislov M. Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition. Zeitschrift fur Anorganische und Allgemeine Chemie. 2024 Jul 29;650(16). e202400032. https://doi.org/10.1002/zaac.202400032

Author

Missyul, A. ; Kreuzer, M. ; Usoltsev, O. ; Arsentev, M. ; Chislov, M. / Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2024 ; Vol. 650, No. 16.

BibTeX

@article{90d6f38fadad49d1ba535d3f32857fc8,
title = "Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition",
abstract = "The double oxalates MI3[MIII(C2O4)3] possess rich crystallochemistry and can be used as precursors for various ceramic materials. The article discusses a case of Li3[Al(C2O4)3]. A series of previously unknown hydrates (Li3[Al(C2O4)3] ⋅ 5.5H2O, Li3[Al(C2O4)3] ⋅ 4H2O, Li3[Al(C2O4)3] ⋅ H2O) was found for this composition, their crystal structure and temperatures of mutual transformations determined. Transformation from Li3[Al(C2O4)3] ⋅ 4H2O to Li3[Al(C2O4)3] ⋅ H2O was found to be accompanied by a change in the topology of the bonding network. Uniaxial negative thermal expansion was found for anhydrous Li3[Al(C2O4)3]. Thermal decomposition of Li3[Al(C2O4)3] was demonstrated to be a promising way to obtain precursors for aluminate ceramics. {\textcopyright} 2024 Wiley-VCH GmbH.",
keywords = "Bridging ligands, Chelates, Hydrates, Oxalates, X-ray diffraction, Crystal structure, Hydration, Lithium compounds, Sodium Aluminate, Thermal expansion, Thermolysis, Chelate, Crystal temperatures, Crystallochemistry, Crystals structures, Hydrate structures, Mutual transformations, Oxalate, Oxalato, X- ray diffractions",
author = "A. Missyul and M. Kreuzer and O. Usoltsev and M. Arsentev and M. Chislov",
note = "Export Date: 19 October 2024 CODEN: ZAACA Адрес для корреспонденции: Missyul, A.; ALBA Synchrotron Light Source, Carrer de La Llum 2–26, Barcelona, Spain; эл. почта: amissiul@cells.es",
year = "2024",
month = jul,
day = "29",
doi = "10.1002/zaac.202400032",
language = "Английский",
volume = "650",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "16",

}

RIS

TY - JOUR

T1 - Lithium Tris(Oxalato)Aaluminate and its Hydrates: Structure, Dehydration and Thermal Decomposition

AU - Missyul, A.

AU - Kreuzer, M.

AU - Usoltsev, O.

AU - Arsentev, M.

AU - Chislov, M.

N1 - Export Date: 19 October 2024 CODEN: ZAACA Адрес для корреспонденции: Missyul, A.; ALBA Synchrotron Light Source, Carrer de La Llum 2–26, Barcelona, Spain; эл. почта: amissiul@cells.es

PY - 2024/7/29

Y1 - 2024/7/29

N2 - The double oxalates MI3[MIII(C2O4)3] possess rich crystallochemistry and can be used as precursors for various ceramic materials. The article discusses a case of Li3[Al(C2O4)3]. A series of previously unknown hydrates (Li3[Al(C2O4)3] ⋅ 5.5H2O, Li3[Al(C2O4)3] ⋅ 4H2O, Li3[Al(C2O4)3] ⋅ H2O) was found for this composition, their crystal structure and temperatures of mutual transformations determined. Transformation from Li3[Al(C2O4)3] ⋅ 4H2O to Li3[Al(C2O4)3] ⋅ H2O was found to be accompanied by a change in the topology of the bonding network. Uniaxial negative thermal expansion was found for anhydrous Li3[Al(C2O4)3]. Thermal decomposition of Li3[Al(C2O4)3] was demonstrated to be a promising way to obtain precursors for aluminate ceramics. © 2024 Wiley-VCH GmbH.

AB - The double oxalates MI3[MIII(C2O4)3] possess rich crystallochemistry and can be used as precursors for various ceramic materials. The article discusses a case of Li3[Al(C2O4)3]. A series of previously unknown hydrates (Li3[Al(C2O4)3] ⋅ 5.5H2O, Li3[Al(C2O4)3] ⋅ 4H2O, Li3[Al(C2O4)3] ⋅ H2O) was found for this composition, their crystal structure and temperatures of mutual transformations determined. Transformation from Li3[Al(C2O4)3] ⋅ 4H2O to Li3[Al(C2O4)3] ⋅ H2O was found to be accompanied by a change in the topology of the bonding network. Uniaxial negative thermal expansion was found for anhydrous Li3[Al(C2O4)3]. Thermal decomposition of Li3[Al(C2O4)3] was demonstrated to be a promising way to obtain precursors for aluminate ceramics. © 2024 Wiley-VCH GmbH.

KW - Bridging ligands

KW - Chelates

KW - Hydrates

KW - Oxalates

KW - X-ray diffraction

KW - Crystal structure

KW - Hydration

KW - Lithium compounds

KW - Sodium Aluminate

KW - Thermal expansion

KW - Thermolysis

KW - Chelate

KW - Crystal temperatures

KW - Crystallochemistry

KW - Crystals structures

KW - Hydrate structures

KW - Mutual transformations

KW - Oxalate

KW - Oxalato

KW - X- ray diffractions

UR - https://www.mendeley.com/catalogue/5a01d0cd-66f2-30b9-9b44-a818e72d821f/

U2 - 10.1002/zaac.202400032

DO - 10.1002/zaac.202400032

M3 - статья

VL - 650

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 16

M1 - e202400032

ER -

ID: 126391473