Standard

Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa : Topology of phase diagrams and nrtl modeling. / Toikka, Maria; Smirnov, Alexander; Samarov, Artemiy.

In: Journal of Chemical and Engineering Data, Vol. 66, No. 3, 11.03.2021, p. 1466-1474.

Research output: Contribution to journal › Article › peer-review

Harvard

Toikka, M, Smirnov, A & Samarov, A 2021, 'Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa: Topology of phase diagrams and nrtl modeling', Journal of Chemical and Engineering Data, vol. 66, no. 3, pp. 1466-1474. https://doi.org/10.1021/acs.jced.0c01066

APA

Toikka, M., Smirnov, A., & Samarov, A. (2021). Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa: Topology of phase diagrams and nrtl modeling. Journal of Chemical and Engineering Data, 66(3), 1466-1474. https://doi.org/10.1021/acs.jced.0c01066

Vancouver

Toikka M, Smirnov A, Samarov A. Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa: Topology of phase diagrams and nrtl modeling. Journal of Chemical and Engineering Data. 2021 Mar 11;66(3):1466-1474. https://doi.org/10.1021/acs.jced.0c01066

Author

Toikka, Maria ; Smirnov, Alexander ; Samarov, Artemiy. / Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa : Topology of phase diagrams and nrtl modeling. In: Journal of Chemical and Engineering Data. 2021 ; Vol. 66, No. 3. pp. 1466-1474.

BibTeX

@article{a6b8d5d607ed4114b275bd8d5575cf10,
title = "Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa: Topology of phase diagrams and nrtl modeling",
abstract = "Compositions of coexisting phases (liquid-liquid equilibrium), solubility, and critical states for the quaternary acetic acid-n-butyl alcohol-n-butyl acetate-water system were carried out at 328.15 K and 101.3 kPa. The results of the work include topological analysis of phase diagrams. The data on liquid phases were determined by gas chromatography analysis. Solubility results and critical compositions were obtained by a {"}cloud-point{"} technique method. Simulation was performed using a nonrandom twoliquid model. Calculated results are in sufficient agreement with experimental data. A comparative analysis of experimental, calculated, and literature data was carried out for binary, ternary, and quaternary mixtures. The location of the critical compositions at different temperatures in the concentration space is discussed. The corresponding phase diagrams are constructed in 2D and 3D concentration spaces. The features of each of the phase diagrams are discussed.",
author = "Maria Toikka and Alexander Smirnov and Artemiy Samarov",
note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society. All rights reserved.",
year = "2021",
month = mar,
day = "11",
doi = "10.1021/acs.jced.0c01066",
language = "English",
volume = "66",
pages = "1466--1474",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Liquid-liquid equilibrium, solubility, and critical states in an acetic acid-n-butyl alcohol-n-butyl acetate-water system at 328.15 k and 101.3 kpa

T2 - Topology of phase diagrams and nrtl modeling

AU - Toikka, Maria

AU - Smirnov, Alexander

AU - Samarov, Artemiy

N1 - Publisher Copyright: © 2021 American Chemical Society. All rights reserved.

PY - 2021/3/11

Y1 - 2021/3/11

N2 - Compositions of coexisting phases (liquid-liquid equilibrium), solubility, and critical states for the quaternary acetic acid-n-butyl alcohol-n-butyl acetate-water system were carried out at 328.15 K and 101.3 kPa. The results of the work include topological analysis of phase diagrams. The data on liquid phases were determined by gas chromatography analysis. Solubility results and critical compositions were obtained by a "cloud-point" technique method. Simulation was performed using a nonrandom twoliquid model. Calculated results are in sufficient agreement with experimental data. A comparative analysis of experimental, calculated, and literature data was carried out for binary, ternary, and quaternary mixtures. The location of the critical compositions at different temperatures in the concentration space is discussed. The corresponding phase diagrams are constructed in 2D and 3D concentration spaces. The features of each of the phase diagrams are discussed.

AB - Compositions of coexisting phases (liquid-liquid equilibrium), solubility, and critical states for the quaternary acetic acid-n-butyl alcohol-n-butyl acetate-water system were carried out at 328.15 K and 101.3 kPa. The results of the work include topological analysis of phase diagrams. The data on liquid phases were determined by gas chromatography analysis. Solubility results and critical compositions were obtained by a "cloud-point" technique method. Simulation was performed using a nonrandom twoliquid model. Calculated results are in sufficient agreement with experimental data. A comparative analysis of experimental, calculated, and literature data was carried out for binary, ternary, and quaternary mixtures. The location of the critical compositions at different temperatures in the concentration space is discussed. The corresponding phase diagrams are constructed in 2D and 3D concentration spaces. The features of each of the phase diagrams are discussed.

UR - http://www.scopus.com/inward/record.url?scp=85103330243&partnerID=8YFLogxK

U2 - 10.1021/acs.jced.0c01066

DO - 10.1021/acs.jced.0c01066

M3 - Article

AN - SCOPUS:85103330243

VL - 66

SP - 1466

EP - 1474

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 3

ER -

ID: 88744696