Standard

Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K. / Samarov, Artemiy; Volodina, Natalia; Prikhodko, Igor; Toikka, Alexander.

In: Journal of Chemical & Engineering Data, Vol. 69, No. 3, 05.08.2024, p. 3103–3110.

Research output: Contribution to journal › Article › peer-review

Harvard

Samarov, A, Volodina, N, Prikhodko, I & Toikka, A 2024, 'Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K', Journal of Chemical & Engineering Data, vol. 69, no. 3, pp. 3103–3110. https://doi.org/10.1021/acs.jced.4c00281

APA

Samarov, A., Volodina, N., Prikhodko, I., & Toikka, A. (2024). Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K. Journal of Chemical & Engineering Data, 69(3), 3103–3110. https://doi.org/10.1021/acs.jced.4c00281

Vancouver

Samarov A, Volodina N, Prikhodko I, Toikka A. Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K. Journal of Chemical & Engineering Data. 2024 Aug 5;69(3): 3103–3110. https://doi.org/10.1021/acs.jced.4c00281

Author

Samarov, Artemiy ; Volodina, Natalia ; Prikhodko, Igor ; Toikka, Alexander. / Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K. In: Journal of Chemical & Engineering Data. 2024 ; Vol. 69, No. 3. pp. 3103–3110.

BibTeX

@article{166df69e86594d9da19242d0a3013d53,
title = "Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K",
abstract = "Deep eutectic solvents (DESs) formed by choline chloride and malonic or glutaric acid were tested for separating azeotropic mixtures. To separate alcohol-ester systems (n-propanol-ethyl formate, n-butanol-ethyl formate), the experimental data of liquid-liquid equilibria (LLE) together with phase diagrams for pseudoternary systems including the DESs were obtained at temperatures of 293.15 and 313.15 K and atmospheric pressure. Liquid-liquid tie lines were determined using NMR spectroscopy and analyzed. Along with LLE data, density and viscosity measurements for the studied DESs in the temperature range of 293.15-353.15 K were carried out. The separation performance of DESs was characterized by distribution coefficients and values of selectivity to alcohol. Comparison of selectivity values in systems containing alcohols and esters and two DESs composed of choline chloride and malonic or glutaric acids was performed. It was found that the studied DESs are capable of catalyzing the transesterification reaction, and the conversion values in the organic phase were determined depending on the alcohol concentration.",
author = "Artemiy Samarov and Natalia Volodina and Igor Prikhodko and Alexander Toikka",
year = "2024",
month = aug,
day = "5",
doi = "10.1021/acs.jced.4c00281",
language = "English",
volume = "69",
pages = " 3103–3110",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Liquid–Liquid Equilibrium in Systems with Transesterification of Alcohol ( n -Propanol Or n -Butanol)–Ethyl Formate with Deep Eutectic Solvent Based on Choline Chloride at 293.15 and 313.15 K

AU - Samarov, Artemiy

AU - Volodina, Natalia

AU - Prikhodko, Igor

AU - Toikka, Alexander

PY - 2024/8/5

Y1 - 2024/8/5

N2 - Deep eutectic solvents (DESs) formed by choline chloride and malonic or glutaric acid were tested for separating azeotropic mixtures. To separate alcohol-ester systems (n-propanol-ethyl formate, n-butanol-ethyl formate), the experimental data of liquid-liquid equilibria (LLE) together with phase diagrams for pseudoternary systems including the DESs were obtained at temperatures of 293.15 and 313.15 K and atmospheric pressure. Liquid-liquid tie lines were determined using NMR spectroscopy and analyzed. Along with LLE data, density and viscosity measurements for the studied DESs in the temperature range of 293.15-353.15 K were carried out. The separation performance of DESs was characterized by distribution coefficients and values of selectivity to alcohol. Comparison of selectivity values in systems containing alcohols and esters and two DESs composed of choline chloride and malonic or glutaric acids was performed. It was found that the studied DESs are capable of catalyzing the transesterification reaction, and the conversion values in the organic phase were determined depending on the alcohol concentration.

AB - Deep eutectic solvents (DESs) formed by choline chloride and malonic or glutaric acid were tested for separating azeotropic mixtures. To separate alcohol-ester systems (n-propanol-ethyl formate, n-butanol-ethyl formate), the experimental data of liquid-liquid equilibria (LLE) together with phase diagrams for pseudoternary systems including the DESs were obtained at temperatures of 293.15 and 313.15 K and atmospheric pressure. Liquid-liquid tie lines were determined using NMR spectroscopy and analyzed. Along with LLE data, density and viscosity measurements for the studied DESs in the temperature range of 293.15-353.15 K were carried out. The separation performance of DESs was characterized by distribution coefficients and values of selectivity to alcohol. Comparison of selectivity values in systems containing alcohols and esters and two DESs composed of choline chloride and malonic or glutaric acids was performed. It was found that the studied DESs are capable of catalyzing the transesterification reaction, and the conversion values in the organic phase were determined depending on the alcohol concentration.

UR - https://www.mendeley.com/catalogue/b4783b1f-c841-3eb7-83e4-2609f3305b20/

U2 - 10.1021/acs.jced.4c00281

DO - 10.1021/acs.jced.4c00281

M3 - Article

VL - 69

SP - 3103

EP - 3110

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 3

ER -

ID: 124949002