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Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5 : Variable-temperature FTIR studies. / Otero Areán, C.; Rodríguez Delgado, M.; Manoilova, O. V.; Turnes Palomino, G.; Tsyganenko, A. A.; Garrone, E.

In: Chemical Physics Letters, Vol. 362, No. 1-2, 13.08.2002, p. 109-113.

Research output: Contribution to journal › Article › peer-review

Harvard

Otero Areán, C, Rodríguez Delgado, M, Manoilova, OV, Turnes Palomino, G, Tsyganenko, AA & Garrone, E 2002, 'Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5: Variable-temperature FTIR studies', Chemical Physics Letters, vol. 362, no. 1-2, pp. 109-113. https://doi.org/10.1016/S0009-2614(02)00985-5

APA

Otero Areán, C., Rodríguez Delgado, M., Manoilova, O. V., Turnes Palomino, G., Tsyganenko, A. A., & Garrone, E. (2002). Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5: Variable-temperature FTIR studies. Chemical Physics Letters, 362(1-2), 109-113. https://doi.org/10.1016/S0009-2614(02)00985-5

Vancouver

Otero Areán C, Rodríguez Delgado M, Manoilova OV, Turnes Palomino G, Tsyganenko AA, Garrone E. Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5: Variable-temperature FTIR studies. Chemical Physics Letters. 2002 Aug 13;362(1-2):109-113. https://doi.org/10.1016/S0009-2614(02)00985-5

Author

Otero Areán, C. ; Rodríguez Delgado, M. ; Manoilova, O. V. ; Turnes Palomino, G. ; Tsyganenko, A. A. ; Garrone, E. / Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5 : Variable-temperature FTIR studies. In: Chemical Physics Letters. 2002 ; Vol. 362, No. 1-2. pp. 109-113.

BibTeX

@article{1f240f0ffe6a4ff8b0c24be867a2565a,
title = "Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5: Variable-temperature FTIR studies",
abstract = "Carbon monoxide adsorbed at a low-temperature on the zeolite Li-ZSM-5 forms Li+ ⋯ CO and Li+ ⋯ (CO)2 species characterized by C-O stretching bands at 2195 and 2187 cm-1, respectively. These C-bonded carbonyls are in a temperature-dependent equilibrium with Li+ ⋯ OC and CO ⋯ Li+ ⋯ CO species having O-bonded CO. By means of variable-temperature FTIR spectroscopy, the enthalpy change involved in the corresponding isomerization process was found to be ΔH° = 7.8 kJ mol-1 for the monocarbonyl and ΔH° = 5.1 kJ mol-1 for the dicarbonyl. Therefore, although C-bonded species were always found to show a higher cation-CO interaction energy than O-bonded species, the difference is smaller in the case of dicarbonyls.",
author = "{Otero Are{\'a}n}, C. and {Rodr{\'i}guez Delgado}, M. and Manoilova, {O. V.} and {Turnes Palomino}, G. and Tsyganenko, {A. A.} and E. Garrone",
year = "2002",
month = aug,
day = "13",
doi = "10.1016/S0009-2614(02)00985-5",
language = "English",
volume = "362",
pages = "109--113",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Linkage isomerism of carbonyl coordination complexes formed upon CO adsorption on the zeolite Li-ZSM-5

T2 - Variable-temperature FTIR studies

AU - Otero Areán, C.

AU - Rodríguez Delgado, M.

AU - Manoilova, O. V.

AU - Turnes Palomino, G.

AU - Tsyganenko, A. A.

AU - Garrone, E.

PY - 2002/8/13

Y1 - 2002/8/13

N2 - Carbon monoxide adsorbed at a low-temperature on the zeolite Li-ZSM-5 forms Li+ ⋯ CO and Li+ ⋯ (CO)2 species characterized by C-O stretching bands at 2195 and 2187 cm-1, respectively. These C-bonded carbonyls are in a temperature-dependent equilibrium with Li+ ⋯ OC and CO ⋯ Li+ ⋯ CO species having O-bonded CO. By means of variable-temperature FTIR spectroscopy, the enthalpy change involved in the corresponding isomerization process was found to be ΔH° = 7.8 kJ mol-1 for the monocarbonyl and ΔH° = 5.1 kJ mol-1 for the dicarbonyl. Therefore, although C-bonded species were always found to show a higher cation-CO interaction energy than O-bonded species, the difference is smaller in the case of dicarbonyls.

AB - Carbon monoxide adsorbed at a low-temperature on the zeolite Li-ZSM-5 forms Li+ ⋯ CO and Li+ ⋯ (CO)2 species characterized by C-O stretching bands at 2195 and 2187 cm-1, respectively. These C-bonded carbonyls are in a temperature-dependent equilibrium with Li+ ⋯ OC and CO ⋯ Li+ ⋯ CO species having O-bonded CO. By means of variable-temperature FTIR spectroscopy, the enthalpy change involved in the corresponding isomerization process was found to be ΔH° = 7.8 kJ mol-1 for the monocarbonyl and ΔH° = 5.1 kJ mol-1 for the dicarbonyl. Therefore, although C-bonded species were always found to show a higher cation-CO interaction energy than O-bonded species, the difference is smaller in the case of dicarbonyls.

UR - http://www.scopus.com/inward/record.url?scp=0037072218&partnerID=8YFLogxK

U2 - 10.1016/S0009-2614(02)00985-5

DO - 10.1016/S0009-2614(02)00985-5

M3 - Article

AN - SCOPUS:0037072218

VL - 362

SP - 109

EP - 113

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-2

ER -

ID: 41680654