• I. M. Grigoriev
  • N. N. Filippov
  • M. V. Tonkov
  • J. P. Champion
  • T. Gabard
  • R. Le Doucen

The IR absorption spectra of CH4 in pure gas and in mixture with helium were studied in the region of ν3 band at higher J line clusters R(17)-R(22). The frequencies and intensities of rotation-vibration lines were estimated from the experimental spectra at Doppler shape conditions. The line frequencies and intensities were calculated and used for the attribution of overlapped lines in clusters. The calculated line intensities are close to the experimental values. The calculated frequency structure of the higher J manifolds are somewhat wider than the observed one. The shapes of helium-broadened line clusters were compared with those calculated accounting for line mixing. The relaxation matrix W, which is necessary in shape calculations, was constructed using semiclassical collision rate constants. The calculated shapes are in satisfactory accordance with the measured ones.

Original languageEnglish
Pages (from-to)431-443
Number of pages13
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume74
Issue number4
DOIs
StatePublished - 15 Aug 2002

    Scopus subject areas

  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

    Research areas

  • Line mixing, Line parameters, Methane, Vibration-rotation spectra

ID: 28680711