A review of papers in the field of the line-mixing effect on IR absorption band shapes is presented, with most attention being paid to work carried out at the Molecular Spectroscopy Laboratory of St. Petersburg University. After general formulation of the problem, the empirical methods of rotational relaxation matrix evaluation are considered, and the strong collision model is discussed in more detail. The method of far band wing calculation, which takes into consideration both line mixing and the finite collision duration effect, shows the important role of line mixing in far wing shape formation. In the Markov approximation, line mixing is considered semiclassically. The classical distribution of the angular momentum alteration probability in collisions is used for reconstruction of Γ matrices which describe line broadening, line shifting and line mixing effects in the discrete rotational state representation. This method is shown to give acceptable results for the prediction of line mixing effects for central regions of Σ-Σ bands of diatomic and linear molecules.

Original languageEnglish
Pages (from-to)901-918
Number of pages18
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume52
Issue number8
DOIs
StatePublished - 1 Jan 1996
EventInternational Conference on Tunable Diode Laser Spectroscopy and Spectroscopy in Russia (TDLS-95) - MOSCOW
Duration: 9 Jul 199511 Jul 1995

    Research areas

  • IR absorption, Line-mixing effect

    Scopus subject areas

  • Analytical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Instrumentation
  • Spectroscopy

ID: 41411025