Line mixing effects have been studied in the v(3) band of CH3F perturbed by helium. Theoretical absorption coefficients are compared to FTIR measurements, which were made at room temperature for helium pressure from 1 atm up to 90 atm. The observed strong modifications with respect to additive Lorentzian contributions are explained by line coupling effects. The Infinite Order Sudden Approximation and the Energy Corrected Sudden Approximation are used in order to account for these effects. The latter gives better agreement: it rather successfully predicts the band shape and the linewidths.

Original languageEnglish
Pages (from-to)343-353
Number of pages11
JournalEuropean Physical Journal D
Volume6
Issue number3
StatePublished - Jun 1999

    Research areas

  • Q-BRANCH ABSORPTION, STIMULATED RAMAN-SPECTROSCOPY, ROTATIONAL ENERGY-TRANSFER, DIODE-LASER MEASUREMENTS, BROADENING COEFFICIENTS, THEORETICAL-ANALYSIS, FOURIER-TRANSFORM, CROSS-SECTIONS, FERMI DYAD, CO2 GAS

ID: 41410055