Limiting current to a rotating disk electrode modified with an electroactive polymeric film in the presence of a redox pair in the adjacent solution volume

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Limiting current to a rotating disk electrode modified with an electroactive polymeric film in the presence of a redox pair in the adjacent solution volume. / Malev, V. V.; Levin, O. V.

In: Russian Journal of Electrochemistry, Vol. 44, No. 1, 01.01.2008, p. 91-97.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{2779d8c15e9c45e489ae2f53a523a708,

title = "Limiting current to a rotating disk electrode modified with an electroactive polymeric film in the presence of a redox pair in the adjacent solution volume",

abstract = "Expressions for the limiting current to a rotating disk electrode modified by a conductive polymeric film are obtained for different localization of a redox process that involves redox species in the bulk of the adjacent solution. For an electrode reaction on the modifying film surface, it is shown that the dependence of the limiting current on the bulk concentration of reacting species is described by a curve with saturation. Such a limitation does not arise for a reaction on the electrode substrate. This can serve as a criterion in location of the reaction zone. In addition, other possible prospects of the use of a rotating disk in studying the charge transfer in electroactive polymeric films are discussed.",

keywords = "Counter ions, Electroactive polymers, Modified electrode, P- and n-doping, Rotating disk electrode",

author = "Malev, {V. V.} and Levin, {O. V.}",

year = "2008",

month = jan,

day = "1",

doi = "10.1007/s11175-008-1013-x",

language = "English",

volume = "44",

pages = "91--97",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "1",

}

RIS

TY - JOUR

T1 - Limiting current to a rotating disk electrode modified with an electroactive polymeric film in the presence of a redox pair in the adjacent solution volume

AU - Malev, V. V.

AU - Levin, O. V.

PY - 2008/1/1

Y1 - 2008/1/1

N2 - Expressions for the limiting current to a rotating disk electrode modified by a conductive polymeric film are obtained for different localization of a redox process that involves redox species in the bulk of the adjacent solution. For an electrode reaction on the modifying film surface, it is shown that the dependence of the limiting current on the bulk concentration of reacting species is described by a curve with saturation. Such a limitation does not arise for a reaction on the electrode substrate. This can serve as a criterion in location of the reaction zone. In addition, other possible prospects of the use of a rotating disk in studying the charge transfer in electroactive polymeric films are discussed.

AB - Expressions for the limiting current to a rotating disk electrode modified by a conductive polymeric film are obtained for different localization of a redox process that involves redox species in the bulk of the adjacent solution. For an electrode reaction on the modifying film surface, it is shown that the dependence of the limiting current on the bulk concentration of reacting species is described by a curve with saturation. Such a limitation does not arise for a reaction on the electrode substrate. This can serve as a criterion in location of the reaction zone. In addition, other possible prospects of the use of a rotating disk in studying the charge transfer in electroactive polymeric films are discussed.

KW - Counter ions

KW - Electroactive polymers

KW - Modified electrode

KW - P- and n-doping

KW - Rotating disk electrode

UR - http://www.scopus.com/inward/record.url?scp=42349087582&partnerID=8YFLogxK

U2 - 10.1007/s11175-008-1013-x

DO - 10.1007/s11175-008-1013-x

M3 - Article

AN - SCOPUS:42349087582

VL - 44

SP - 91

EP - 97

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 1

ER -

ID: 36236163