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Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes. / Markovski, Mishel R.; Siidra, Oleg I. ; Charkin, Dmitri O.; Vladimirova, Victoria A. ; Tsirlin, Alexander A.; Grishaev, Vasili Yu.

In: Dalton Transactions, No. 49, 11.05.2020, p. 7790-7795.

Research output: Contribution to journal › Article › peer-review

Harvard

Markovski, MR, Siidra, OI, Charkin, DO, Vladimirova, VA, Tsirlin, AA & Grishaev, VY 2020, 'Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes', Dalton Transactions, no. 49, pp. 7790-7795.

APA

Markovski, M. R., Siidra, O. I., Charkin, D. O., Vladimirova, V. A., Tsirlin, A. A., & Grishaev, V. Y. (2020). Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes. Dalton Transactions, (49), 7790-7795.

Vancouver

Markovski MR, Siidra OI, Charkin DO, Vladimirova VA, Tsirlin AA, Grishaev VY. Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes. Dalton Transactions. 2020 May 11;(49):7790-7795.

Author

Markovski, Mishel R. ; Siidra, Oleg I. ; Charkin, Dmitri O. ; Vladimirova, Victoria A. ; Tsirlin, Alexander A. ; Grishaev, Vasili Yu. / Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes. In: Dalton Transactions. 2020 ; No. 49. pp. 7790-7795.

BibTeX

@article{c3b45585c6e64a0e8c836a2dd2488bfe,
title = "Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes",
abstract = "A new lithium copper diselenite chloride hydrate, Li2Se2O5(H2O)1.5·CuCl2, was prepared from aqueoussolution. Its unique 2D structure can be interpreted as Li2Se2O5(H2O)1.5 layers with CuCl2 hosts embeddedin the interlayer space, and be considered halfway between the salt-inclusion and host–guest structures.The CuO2Cl4 octahedra form chains similar to those in CuCl2·2H2O, yet water molecules are coordinatedexclusively to Li+ while Se2O52− and Cl− bridge Li+ and Cu2+. The complexity of the structure is likelyresponsible for both very long pre-crystallization time and non-existence of the corresponding bromideanalogue. Despite the relatively long Cu⋯Cu separations, the compound exhibits weak ferromagneticinteractions along the chains of CuO2Cl4 octahedra.",
author = "Markovski, {Mishel R.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Vladimirova, {Victoria A.} and Tsirlin, {Alexander A.} and Grishaev, {Vasili Yu}",
year = "2020",
month = may,
day = "11",
language = "English",
pages = "7790--7795",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "49",

}

RIS

TY - JOUR

T1 - Li2(Se2O5)(H2O)1.5·CuCl2, a salt-inclusion diselenite structurally based on tetranuclear Li4 complexes

AU - Markovski, Mishel R.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Vladimirova, Victoria A.

AU - Tsirlin, Alexander A.

AU - Grishaev, Vasili Yu

PY - 2020/5/11

Y1 - 2020/5/11

N2 - A new lithium copper diselenite chloride hydrate, Li2Se2O5(H2O)1.5·CuCl2, was prepared from aqueoussolution. Its unique 2D structure can be interpreted as Li2Se2O5(H2O)1.5 layers with CuCl2 hosts embeddedin the interlayer space, and be considered halfway between the salt-inclusion and host–guest structures.The CuO2Cl4 octahedra form chains similar to those in CuCl2·2H2O, yet water molecules are coordinatedexclusively to Li+ while Se2O52− and Cl− bridge Li+ and Cu2+. The complexity of the structure is likelyresponsible for both very long pre-crystallization time and non-existence of the corresponding bromideanalogue. Despite the relatively long Cu⋯Cu separations, the compound exhibits weak ferromagneticinteractions along the chains of CuO2Cl4 octahedra.

AB - A new lithium copper diselenite chloride hydrate, Li2Se2O5(H2O)1.5·CuCl2, was prepared from aqueoussolution. Its unique 2D structure can be interpreted as Li2Se2O5(H2O)1.5 layers with CuCl2 hosts embeddedin the interlayer space, and be considered halfway between the salt-inclusion and host–guest structures.The CuO2Cl4 octahedra form chains similar to those in CuCl2·2H2O, yet water molecules are coordinatedexclusively to Li+ while Se2O52− and Cl− bridge Li+ and Cu2+. The complexity of the structure is likelyresponsible for both very long pre-crystallization time and non-existence of the corresponding bromideanalogue. Despite the relatively long Cu⋯Cu separations, the compound exhibits weak ferromagneticinteractions along the chains of CuO2Cl4 octahedra.

M3 - Article

SP - 7790

EP - 7795

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 49

ER -

ID: 87606626