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Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine : A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols. / Rodionov, Ivan A.; Maksimova, Elizaveta A.; Pozhidaev, Artem Y.; Kurnosenko, Sergey A.; Silyukov, Oleg I.; Zvereva, Irina A.

In: Frontiers in Chemistry, Vol. 7, 863, 12.12.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Rodionov, IA, Maksimova, EA, Pozhidaev, AY, Kurnosenko, SA, Silyukov, OI & Zvereva, IA 2019, 'Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine: A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols', Frontiers in Chemistry, vol. 7, 863. https://doi.org/10.3389/fchem.2019.00863

APA

Rodionov, I. A., Maksimova, E. A., Pozhidaev, A. Y., Kurnosenko, S. A., Silyukov, O. I., & Zvereva, I. A. (2019). Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine: A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols. Frontiers in Chemistry, 7, [863]. https://doi.org/10.3389/fchem.2019.00863

Vancouver

Rodionov IA, Maksimova EA, Pozhidaev AY, Kurnosenko SA, Silyukov OI, Zvereva IA. Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine: A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols. Frontiers in Chemistry. 2019 Dec 12;7. 863. https://doi.org/10.3389/fchem.2019.00863

Author

Rodionov, Ivan A. ; Maksimova, Elizaveta A. ; Pozhidaev, Artem Y. ; Kurnosenko, Sergey A. ; Silyukov, Oleg I. ; Zvereva, Irina A. / Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine : A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols. In: Frontiers in Chemistry. 2019 ; Vol. 7.

BibTeX

@article{5478b9ea51c64836849b8b4ae4a0a7cc,
title = "Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine: A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols",
abstract = "A layered perovskite-type oxide intercalated with n-butylamine is reported as an efficient photocatalyst for hydrogen production from aqueous solutions of alcohols for the first time. The hybrid photocatalyst H2Nd2Ti3O10×BuNH2 was synthesized by solid-state ceramic method followed by protonation, intercalation of methylamine and subsequent substitution by n-butylamine. The product was characterized by powder XRD, TGA, STA-MS, DRS, IR, and Raman spectroscopy, CHN analysis, SEM. Intercalation of n-butylamine caused a dramatic increase in photocatalytic activity of H2Nd2Ti3O10 in the reaction of hydrogen evolution from aqueous solutions of methanol, ethanol, and n-butanol under UV radiation. While the non-intercalated Pt-loaded H2Nd2Ti3O10 showed a maximum quantum efficiency of only 2% in the 220–340 nm range, the efficiency for hybrid samples reached 23% under the same conditions and after variation of experimental parameters even 52% efficiency was achieved. This effect may be associated with the significant expansion of the interlayer space, which is considered as a separate reaction zone.",
keywords = "amine, hybrid compounds, hydrogen production, intercalation, layered titanate, perovskite-type structure, photocatalysis",
author = "Rodionov, {Ivan A.} and Maksimova, {Elizaveta A.} and Pozhidaev, {Artem Y.} and Kurnosenko, {Sergey A.} and Silyukov, {Oleg I.} and Zvereva, {Irina A.}",
year = "2019",
month = dec,
day = "12",
doi = "10.3389/fchem.2019.00863",
language = "English",
volume = "7",
journal = "Frontiers in Chemistry",
issn = "2296-2646",
publisher = "Frontiers Media S.A.",

}

RIS

TY - JOUR

T1 - Layered Titanate H2Nd2Ti3O10 Intercalated With n-Butylamine

T2 - A New Highly Efficient Hybrid Photocatalyst for Hydrogen Production From Aqueous Solutions of Alcohols

AU - Rodionov, Ivan A.

AU - Maksimova, Elizaveta A.

AU - Pozhidaev, Artem Y.

AU - Kurnosenko, Sergey A.

AU - Silyukov, Oleg I.

AU - Zvereva, Irina A.

PY - 2019/12/12

Y1 - 2019/12/12

N2 - A layered perovskite-type oxide intercalated with n-butylamine is reported as an efficient photocatalyst for hydrogen production from aqueous solutions of alcohols for the first time. The hybrid photocatalyst H2Nd2Ti3O10×BuNH2 was synthesized by solid-state ceramic method followed by protonation, intercalation of methylamine and subsequent substitution by n-butylamine. The product was characterized by powder XRD, TGA, STA-MS, DRS, IR, and Raman spectroscopy, CHN analysis, SEM. Intercalation of n-butylamine caused a dramatic increase in photocatalytic activity of H2Nd2Ti3O10 in the reaction of hydrogen evolution from aqueous solutions of methanol, ethanol, and n-butanol under UV radiation. While the non-intercalated Pt-loaded H2Nd2Ti3O10 showed a maximum quantum efficiency of only 2% in the 220–340 nm range, the efficiency for hybrid samples reached 23% under the same conditions and after variation of experimental parameters even 52% efficiency was achieved. This effect may be associated with the significant expansion of the interlayer space, which is considered as a separate reaction zone.

AB - A layered perovskite-type oxide intercalated with n-butylamine is reported as an efficient photocatalyst for hydrogen production from aqueous solutions of alcohols for the first time. The hybrid photocatalyst H2Nd2Ti3O10×BuNH2 was synthesized by solid-state ceramic method followed by protonation, intercalation of methylamine and subsequent substitution by n-butylamine. The product was characterized by powder XRD, TGA, STA-MS, DRS, IR, and Raman spectroscopy, CHN analysis, SEM. Intercalation of n-butylamine caused a dramatic increase in photocatalytic activity of H2Nd2Ti3O10 in the reaction of hydrogen evolution from aqueous solutions of methanol, ethanol, and n-butanol under UV radiation. While the non-intercalated Pt-loaded H2Nd2Ti3O10 showed a maximum quantum efficiency of only 2% in the 220–340 nm range, the efficiency for hybrid samples reached 23% under the same conditions and after variation of experimental parameters even 52% efficiency was achieved. This effect may be associated with the significant expansion of the interlayer space, which is considered as a separate reaction zone.

KW - amine

KW - hybrid compounds

KW - hydrogen production

KW - intercalation

KW - layered titanate

KW - perovskite-type structure

KW - photocatalysis

UR - http://www.scopus.com/inward/record.url?scp=85077265089&partnerID=8YFLogxK

U2 - 10.3389/fchem.2019.00863

DO - 10.3389/fchem.2019.00863

M3 - Article

AN - SCOPUS:85077265089

VL - 7

JO - Frontiers in Chemistry

JF - Frontiers in Chemistry

SN - 2296-2646

M1 - 863

ER -

ID: 51342315