Research output: Contribution to journal › Article › peer-review
Laser-induced synthesis of composite materials based on iridium, gold and platinum for non-enzymatic glucose sensing. / Panov, Maxim S.; Khairullina, Evgeniia M.; Vshivtcev, Filipp S.; Ryazantsev, Mikhail N.; Tumkin, Ilya I.
In: Materials, Vol. 13, No. 15, 3359, 08.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Laser-induced synthesis of composite materials based on iridium, gold and platinum for non-enzymatic glucose sensing
AU - Panov, Maxim S.
AU - Khairullina, Evgeniia M.
AU - Vshivtcev, Filipp S.
AU - Ryazantsev, Mikhail N.
AU - Tumkin, Ilya I.
N1 - Publisher Copyright: © 2020 by the authors.
PY - 2020/8
Y1 - 2020/8
N2 - A simple approach for in situ laser-induced modification of iridium-based materials to increase their electrocatalytic activity towards enzyme-free glucose sensing was proposed. For this purpose, we deposited gold and platinum separately and as a mixture on the surface of pre-synthesized iridium microstructures upon laser irradiation at a wavelength of 532 nm. Then, we carried out the comparative investigation of their morphology, elemental and phase composition as well as their electrochemical properties. The best morphology and, as a result, the highest sensitivity (~9960 μA/mM cm2) with respect to non-enzymatic determination of D-glucose were demonstrated by iridium-gold-platinum microstructures also showing low limit of detection (~0.12 μM), a wide linear range (0.5 μM-1 mM) along with good selectivity, reproducibility and stability.
AB - A simple approach for in situ laser-induced modification of iridium-based materials to increase their electrocatalytic activity towards enzyme-free glucose sensing was proposed. For this purpose, we deposited gold and platinum separately and as a mixture on the surface of pre-synthesized iridium microstructures upon laser irradiation at a wavelength of 532 nm. Then, we carried out the comparative investigation of their morphology, elemental and phase composition as well as their electrochemical properties. The best morphology and, as a result, the highest sensitivity (~9960 μA/mM cm2) with respect to non-enzymatic determination of D-glucose were demonstrated by iridium-gold-platinum microstructures also showing low limit of detection (~0.12 μM), a wide linear range (0.5 μM-1 mM) along with good selectivity, reproducibility and stability.
KW - Composites
KW - Enzyme-free sensing
KW - Glucose
KW - Gold
KW - Iridium
KW - Laser-induced deposition of metal microstructures
KW - Platinum
KW - OXIDATION
KW - glucose
KW - NANOFIBERS
KW - DEPOSITION
KW - MICROCOMPOSITE
KW - NANOCRYSTALS
KW - COPPER
KW - laser-induced deposition of metal microstructures
KW - SENSORS
KW - enzyme-free sensing
KW - iridium
KW - gold
KW - composites
KW - NANOPARTICLES
KW - platinum
KW - FABRICATION
KW - BIOSENSOR
UR - http://www.scopus.com/inward/record.url?scp=85089741054&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/130fbf52-60af-3ea9-ab9e-257292b3e01d/
U2 - 10.3390/ma13153359
DO - 10.3390/ma13153359
M3 - Article
AN - SCOPUS:85089741054
VL - 13
JO - Materials
JF - Materials
SN - 1996-1944
IS - 15
M1 - 3359
ER -
ID: 62176535