Research output: Contribution to journal › Article › peer-review
Kinetics of intermediate phase growth at the interface of fluoride-conducting solid electrolytes with metal electrodes. / Turaeva, M. S.; Tarasenkova, I. V.; Glumov, O. V.; Murin, I. V.
In: Russian Journal of Electrochemistry, Vol. 49, No. 7, 07.2013, p. 712-717.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Kinetics of intermediate phase growth at the interface of fluoride-conducting solid electrolytes with metal electrodes
AU - Turaeva, M. S.
AU - Tarasenkova, I. V.
AU - Glumov, O. V.
AU - Murin, I. V.
PY - 2013/7
Y1 - 2013/7
N2 - The effect of the reference electrode (Ag, AgClâ̂£KF + KCl or Sn, SnF2) on the kinetics of new phase growth at interfaces formed by LaF3:Eu2+ or CeF3:Sr2+ single crystal solid electrolytes with metal electrodes of Ag and Bi is studied by chronoamperometry and linear scan voltammetry. It is shown that when a solid-phase reference electrode is used, the current transients reflect hindrances associated with instantaneous two- or three-dimensional nucleation as well as limitations for fluoride ion diffusion in the solid electrolyte.
AB - The effect of the reference electrode (Ag, AgClâ̂£KF + KCl or Sn, SnF2) on the kinetics of new phase growth at interfaces formed by LaF3:Eu2+ or CeF3:Sr2+ single crystal solid electrolytes with metal electrodes of Ag and Bi is studied by chronoamperometry and linear scan voltammetry. It is shown that when a solid-phase reference electrode is used, the current transients reflect hindrances associated with instantaneous two- or three-dimensional nucleation as well as limitations for fluoride ion diffusion in the solid electrolyte.
KW - bismuth
KW - cerium fluoride
KW - chronoamperometry
KW - lanthanum fluoride
KW - new phase growth
KW - potentiostatic current transients
KW - silver
KW - solid electrolytes
UR - http://www.scopus.com/inward/record.url?scp=84880290919&partnerID=8YFLogxK
U2 - 10.1134/S1023193513070185
DO - 10.1134/S1023193513070185
M3 - Article
VL - 49
SP - 712
EP - 717
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 7
ER -
ID: 7396554