Kinetics of decarbonylation of pentacarbonyltechnetium halides in solution

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Kinetics of decarbonylation of pentacarbonyltechnetium halides in solution. / Miroslavov, A. E.; Sidorenko, G. V.; Lumpov, A. A.; Mikhalev, V. A.; Suglobov, D. N.

In: Radiochemistry, Vol. 51, No. 1, 02.2009, p. 5-10.

Research output: Contribution to journal › Article › peer-review

Author

Miroslavov, A. E. ; Sidorenko, G. V. ; Lumpov, A. A. ; Mikhalev, V. A. ; Suglobov, D. N. / Kinetics of decarbonylation of pentacarbonyltechnetium halides in solution. In: Radiochemistry. 2009 ; Vol. 51, No. 1. pp. 5-10.

BibTeX

@article{67cd464b06b34dafb12439ba3e8988f4,

title = "Kinetics of decarbonylation of pentacarbonyltechnetium halides in solution",

abstract = "The kinetics of decarbonylation of pentacarbonyltechnetium halides TcX(CO)5 (X = Cl, Br, I) in CCl4 solution with the formation of dimers [TcX(CO)4]2 and of CO substitution in TcBr(CO)5 by the solvent molecule in CH3CN solution with the formation of the complex TcBr(CO)3(CH3CN)2 was studied. In all the systems, the reaction is first-order with respect to the starting compound. It was concluded that the limiting step of the reaction is dissociation into the intermediate complex TcX(CO)4 and CO molecule. The rate constants and activation energies of the reactions were determined.",

author = "Miroslavov, {A. E.} and Sidorenko, {G. V.} and Lumpov, {A. A.} and Mikhalev, {V. A.} and Suglobov, {D. N.}",

year = "2009",

month = feb,

doi = "10.1134/S1066362209010020",

language = "English",

volume = "51",

pages = "5--10",

journal = "Radiochemistry",

issn = "1066-3622",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "1",

}

RIS

TY - JOUR

T1 - Kinetics of decarbonylation of pentacarbonyltechnetium halides in solution

AU - Miroslavov, A. E.

AU - Sidorenko, G. V.

AU - Lumpov, A. A.

AU - Mikhalev, V. A.

AU - Suglobov, D. N.

PY - 2009/2

Y1 - 2009/2

N2 - The kinetics of decarbonylation of pentacarbonyltechnetium halides TcX(CO)5 (X = Cl, Br, I) in CCl4 solution with the formation of dimers [TcX(CO)4]2 and of CO substitution in TcBr(CO)5 by the solvent molecule in CH3CN solution with the formation of the complex TcBr(CO)3(CH3CN)2 was studied. In all the systems, the reaction is first-order with respect to the starting compound. It was concluded that the limiting step of the reaction is dissociation into the intermediate complex TcX(CO)4 and CO molecule. The rate constants and activation energies of the reactions were determined.

AB - The kinetics of decarbonylation of pentacarbonyltechnetium halides TcX(CO)5 (X = Cl, Br, I) in CCl4 solution with the formation of dimers [TcX(CO)4]2 and of CO substitution in TcBr(CO)5 by the solvent molecule in CH3CN solution with the formation of the complex TcBr(CO)3(CH3CN)2 was studied. In all the systems, the reaction is first-order with respect to the starting compound. It was concluded that the limiting step of the reaction is dissociation into the intermediate complex TcX(CO)4 and CO molecule. The rate constants and activation energies of the reactions were determined.

UR - http://www.scopus.com/inward/record.url?scp=66749160326&partnerID=8YFLogxK

U2 - 10.1134/S1066362209010020

DO - 10.1134/S1066362209010020

M3 - Article

AN - SCOPUS:66749160326

VL - 51

SP - 5

EP - 10

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 1

ER -

ID: 76835371