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Kinetic model for multi-temperature flows of reacting carbon dioxide mixture. / Kustova, E.; Nagnibeda, E.

In: Chemical Physics, Vol. 398, 04.04.2012, p. 111-117.

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@article{724827aaef804243b6df0faa50efc88e,
title = "Kinetic model for multi-temperature flows of reacting carbon dioxide mixture",
abstract = "In this paper the kinetic description of a viscous reacting flow of CO2/CO/O-2/C/O mixture is proposed on the basis of the kinetic theory methods. Vibrational excitation of CO2, CO and O-2 molecules as well as non-equilibrium dissociation, recombination and exchange reactions are taken into account. A five-temperature model for a non-equilibrium flow is derived from the kinetic theory and used for evaluation of transport properties of the considered mixture at different temperatures and mixture composition. The paper presents the closed set of equations for macroscopic parameters, expressions for transport and source terms suitable for numerical simulations and results of calculations. The influence of non-equilibrium kinetics and mixture composition on transport properties in a flow is discussed. (C) 2011 Elsevier B.V. All rights reserved.",
keywords = "Vibrational kinetics, Transport properties, Non-equilibrium CO2 flows, Five-temperature model, VIBRATIONAL-RELAXATION, DISSOCIATION",
author = "E. Kustova and E. Nagnibeda",
year = "2012",
month = apr,
day = "4",
doi = "10.1016/j.chemphys.2011.05.019",
language = "Английский",
volume = "398",
pages = "111--117",
journal = "Chemical Physics",
issn = "0301-0104",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Kinetic model for multi-temperature flows of reacting carbon dioxide mixture

AU - Kustova, E.

AU - Nagnibeda, E.

PY - 2012/4/4

Y1 - 2012/4/4

N2 - In this paper the kinetic description of a viscous reacting flow of CO2/CO/O-2/C/O mixture is proposed on the basis of the kinetic theory methods. Vibrational excitation of CO2, CO and O-2 molecules as well as non-equilibrium dissociation, recombination and exchange reactions are taken into account. A five-temperature model for a non-equilibrium flow is derived from the kinetic theory and used for evaluation of transport properties of the considered mixture at different temperatures and mixture composition. The paper presents the closed set of equations for macroscopic parameters, expressions for transport and source terms suitable for numerical simulations and results of calculations. The influence of non-equilibrium kinetics and mixture composition on transport properties in a flow is discussed. (C) 2011 Elsevier B.V. All rights reserved.

AB - In this paper the kinetic description of a viscous reacting flow of CO2/CO/O-2/C/O mixture is proposed on the basis of the kinetic theory methods. Vibrational excitation of CO2, CO and O-2 molecules as well as non-equilibrium dissociation, recombination and exchange reactions are taken into account. A five-temperature model for a non-equilibrium flow is derived from the kinetic theory and used for evaluation of transport properties of the considered mixture at different temperatures and mixture composition. The paper presents the closed set of equations for macroscopic parameters, expressions for transport and source terms suitable for numerical simulations and results of calculations. The influence of non-equilibrium kinetics and mixture composition on transport properties in a flow is discussed. (C) 2011 Elsevier B.V. All rights reserved.

KW - Vibrational kinetics

KW - Transport properties

KW - Non-equilibrium CO2 flows

KW - Five-temperature model

KW - VIBRATIONAL-RELAXATION

KW - DISSOCIATION

U2 - 10.1016/j.chemphys.2011.05.019

DO - 10.1016/j.chemphys.2011.05.019

M3 - статья

VL - 398

SP - 111

EP - 117

JO - Chemical Physics

JF - Chemical Physics

SN - 0301-0104

ER -

ID: 5291747