Research output: Contribution to journal › Review article › peer-review
Key Features of TEMPO-Containing Polymers for Energy Storage and Catalytic Systems. / Vereshchagin, Anatoliy A.; Kalnin, Arseniy Y.; Volkov, Alexey I.; Lukyanov, Daniil A.; Levin, Oleg V.
In: Energies, Vol. 15, No. 7, 2699, 06.04.2022.Research output: Contribution to journal › Review article › peer-review
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TY - JOUR
T1 - Key Features of TEMPO-Containing Polymers for Energy Storage and Catalytic Systems
AU - Vereshchagin, Anatoliy A.
AU - Kalnin, Arseniy Y.
AU - Volkov, Alexey I.
AU - Lukyanov, Daniil A.
AU - Levin, Oleg V.
N1 - Vereshchagin, A.A.; Kalnin, A.Y.; Volkov, A.I.; Lukyanov, D.A.; Levin, O.V. Key Features of TEMPO-Containing Polymers for Energy Storage and Catalytic Systems. Energies 2022, 15, 2699. https://doi.org/10.3390/en15072699
PY - 2022/4/6
Y1 - 2022/4/6
N2 - The need for environmentally benign portable energy storage drives research on organic batteries and catalytic systems. These systems are a promising replacement for commonly used energy storage devices that rely on limited resources such as lithium and rare earth metals. The redox-active TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) fragment is a popular component of organic systems, as its benefits include remarkable electrochemical performance and decent physical properties. TEMPO is also known to be an efficient catalyst for alcohol oxidation, oxygen reduction, and various complex organic reactions. It can be attached to various aliphatic and conductive polymers to form high-loading catalysis systems. The performance and efficiency of TEMPO-containing materials strongly depend on the molecular structure, and thus rational design of such compounds is vital for successful implementation. We discuss synthetic approaches for producing electroactive polymers based on conductive and non-conductive backbones with organic radical substituents, fundamental aspects of electrochemistry of such materials, and their application in energy storage devices, such as batteries, redox-flow cells, and electrocatalytic systems. We compare the performance of the materials with different architectures, providing an overview of diverse charge interactions for hybrid materials, and presenting promising research opportunities for the future of this area.
AB - The need for environmentally benign portable energy storage drives research on organic batteries and catalytic systems. These systems are a promising replacement for commonly used energy storage devices that rely on limited resources such as lithium and rare earth metals. The redox-active TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) fragment is a popular component of organic systems, as its benefits include remarkable electrochemical performance and decent physical properties. TEMPO is also known to be an efficient catalyst for alcohol oxidation, oxygen reduction, and various complex organic reactions. It can be attached to various aliphatic and conductive polymers to form high-loading catalysis systems. The performance and efficiency of TEMPO-containing materials strongly depend on the molecular structure, and thus rational design of such compounds is vital for successful implementation. We discuss synthetic approaches for producing electroactive polymers based on conductive and non-conductive backbones with organic radical substituents, fundamental aspects of electrochemistry of such materials, and their application in energy storage devices, such as batteries, redox-flow cells, and electrocatalytic systems. We compare the performance of the materials with different architectures, providing an overview of diverse charge interactions for hybrid materials, and presenting promising research opportunities for the future of this area.
KW - conductive polymers
KW - electrocatalysis
KW - energy storage
KW - molecular structure
KW - nitroxyl
KW - power sources
KW - redox polymers
KW - stable radicals
KW - TEMPO
UR - http://www.scopus.com/inward/record.url?scp=85128446558&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/e6736379-2687-31f6-9efb-a8d27f308f5d/
U2 - 10.3390/en15072699
DO - 10.3390/en15072699
M3 - Review article
AN - SCOPUS:85128446558
VL - 15
JO - Energies
JF - Energies
SN - 1996-1073
IS - 7
M1 - 2699
ER -
ID: 94897582