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Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications. / Деникаев, Андрей; Кузнецова, Юлия Викторовна; Быков, Алексей Геннадьевич; Жиляков, Аркадий; Белова, Ксения ; Абрамов, Павел; Москаленко, Николай; Скорб, Екатерина; Гржегоржевский, Кирилл.

In: ACS Applied Materials and Interfaces, Vol. 16, No. 6, 01.02.2024, p. 7430–7443.

Research output: Contribution to journal › Article › peer-review

Harvard

Деникаев, А, Кузнецова, ЮВ, Быков, АГ, Жиляков, А, Белова, К, Абрамов, П, Москаленко, Н, Скорб, Е & Гржегоржевский, К 2024, 'Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications', ACS Applied Materials and Interfaces, vol. 16, no. 6, pp. 7430–7443. https://doi.org/10.1021/acsami.3c16374

APA

Деникаев, А., Кузнецова, Ю. В., Быков, А. Г., Жиляков, А., Белова, К., Абрамов, П., Москаленко, Н., Скорб, Е., & Гржегоржевский, К. (2024). Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications. ACS Applied Materials and Interfaces, 16(6), 7430–7443. https://doi.org/10.1021/acsami.3c16374

Vancouver

Деникаев А, Кузнецова ЮВ, Быков АГ, Жиляков А, Белова К, Абрамов П et al. Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications. ACS Applied Materials and Interfaces. 2024 Feb 1;16(6):7430–7443. https://doi.org/10.1021/acsami.3c16374

Author

Деникаев, Андрей ; Кузнецова, Юлия Викторовна ; Быков, Алексей Геннадьевич ; Жиляков, Аркадий ; Белова, Ксения ; Абрамов, Павел ; Москаленко, Николай ; Скорб, Екатерина ; Гржегоржевский, Кирилл. / Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications. In: ACS Applied Materials and Interfaces. 2024 ; Vol. 16, No. 6. pp. 7430–7443.

BibTeX

@article{f7ff48d346cb42bfade354c9eee113c9,
title = "Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications",
abstract = "Self-assembly gives rise to the versatile strategies of smart material design but requires precise control on the supramolecular level. Here, inorganic-organic synthons (conjugates) are produced by covalently grafting stearic acid tails to giant polyoxometalate (POM) Keplerate-type {Mo132} through an organosilicon linker (3-aminopropyltrimethoxysilane, APTMS). Using the liposome production approach, the synthons self-assemble to form hollow nanosized vesicles (100-200 nm in diameter), which can be loaded with organic dyes─eriochrome black T (ErChB) and fluorescein (FL)─where the POM layer serves as a membrane with subnanopores for cell-like communication. The dye structure plays an essential role in embedding dyes into the vesicle{\textquoteright}s shell, which opens the way to control the colloidal stability of the system. The produced vesicles are moved by an electric field and used for the creation of an infochemistry scheme with three types of logic gates (AND, OR, and IMP). To design 2D materials, synthons can form spread films, from simple addition on the water-air interface to lateral compression in the Langmuir bath, and highly ordered structures appear, demonstrating electron diffraction in Langmuir-Schaefer (LS) films. These results show the significant potential of POM-based synthons and nanosized vesicles to supramolecular design the diversity of smart materials.",
keywords = "Keplerate, conjugate, infochemistry, polyoxometalate, self-assembly, vesicle",
author = "Андрей Деникаев and Кузнецова, {Юлия Викторовна} and Быков, {Алексей Геннадьевич} and Аркадий Жиляков and Ксения Белова and Павел Абрамов and Николай Москаленко and Екатерина Скорб and Кирилл Гржегоржевский",
year = "2024",
month = feb,
day = "1",
doi = "10.1021/acsami.3c16374",
language = "English",
volume = "16",
pages = "7430–7443",
journal = "ACS applied materials & interfaces",
issn = "1944-8244",
publisher = "American Chemical Society",
number = "6",

}

RIS

TY - JOUR

T1 - Keplerate {Mo132}–Stearic Acid Conjugates: Supramolecular Synthons for the Design of Dye-Loaded Nanovesicles, Langmuir–Schaefer Films, and Infochemical Applications

AU - Деникаев, Андрей

AU - Кузнецова, Юлия Викторовна

AU - Быков, Алексей Геннадьевич

AU - Жиляков, Аркадий

AU - Белова, Ксения

AU - Абрамов, Павел

AU - Москаленко, Николай

AU - Скорб, Екатерина

AU - Гржегоржевский, Кирилл

PY - 2024/2/1

Y1 - 2024/2/1

N2 - Self-assembly gives rise to the versatile strategies of smart material design but requires precise control on the supramolecular level. Here, inorganic-organic synthons (conjugates) are produced by covalently grafting stearic acid tails to giant polyoxometalate (POM) Keplerate-type {Mo132} through an organosilicon linker (3-aminopropyltrimethoxysilane, APTMS). Using the liposome production approach, the synthons self-assemble to form hollow nanosized vesicles (100-200 nm in diameter), which can be loaded with organic dyes─eriochrome black T (ErChB) and fluorescein (FL)─where the POM layer serves as a membrane with subnanopores for cell-like communication. The dye structure plays an essential role in embedding dyes into the vesicle’s shell, which opens the way to control the colloidal stability of the system. The produced vesicles are moved by an electric field and used for the creation of an infochemistry scheme with three types of logic gates (AND, OR, and IMP). To design 2D materials, synthons can form spread films, from simple addition on the water-air interface to lateral compression in the Langmuir bath, and highly ordered structures appear, demonstrating electron diffraction in Langmuir-Schaefer (LS) films. These results show the significant potential of POM-based synthons and nanosized vesicles to supramolecular design the diversity of smart materials.

AB - Self-assembly gives rise to the versatile strategies of smart material design but requires precise control on the supramolecular level. Here, inorganic-organic synthons (conjugates) are produced by covalently grafting stearic acid tails to giant polyoxometalate (POM) Keplerate-type {Mo132} through an organosilicon linker (3-aminopropyltrimethoxysilane, APTMS). Using the liposome production approach, the synthons self-assemble to form hollow nanosized vesicles (100-200 nm in diameter), which can be loaded with organic dyes─eriochrome black T (ErChB) and fluorescein (FL)─where the POM layer serves as a membrane with subnanopores for cell-like communication. The dye structure plays an essential role in embedding dyes into the vesicle’s shell, which opens the way to control the colloidal stability of the system. The produced vesicles are moved by an electric field and used for the creation of an infochemistry scheme with three types of logic gates (AND, OR, and IMP). To design 2D materials, synthons can form spread films, from simple addition on the water-air interface to lateral compression in the Langmuir bath, and highly ordered structures appear, demonstrating electron diffraction in Langmuir-Schaefer (LS) films. These results show the significant potential of POM-based synthons and nanosized vesicles to supramolecular design the diversity of smart materials.

KW - Keplerate

KW - conjugate

KW - infochemistry

KW - polyoxometalate

KW - self-assembly

KW - vesicle

UR - https://www.mendeley.com/catalogue/65fed32a-4116-3d01-928b-6e4de9db5575/

U2 - 10.1021/acsami.3c16374

DO - 10.1021/acsami.3c16374

M3 - Article

VL - 16

SP - 7430

EP - 7443

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

SN - 1944-8244

IS - 6

ER -

ID: 116835943