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Keep it tight : A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes. / Paderina, Aleksandra V.; Koshevoy, Igor O.; Grachova, Elena V.

In: Dalton Transactions, Vol. 50, No. 18, 14.05.2021, p. 6003-6033.

Research output: Contribution to journal › Review article › peer-review

Harvard

Paderina, AV, Koshevoy, IO & Grachova, EV 2021, 'Keep it tight: A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes', Dalton Transactions, vol. 50, no. 18, pp. 6003-6033. https://doi.org/10.1039/d1dt00749a

APA

Paderina, A. V., Koshevoy, I. O., & Grachova, E. V. (2021). Keep it tight: A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes. Dalton Transactions, 50(18), 6003-6033. https://doi.org/10.1039/d1dt00749a

Vancouver

Paderina AV, Koshevoy IO, Grachova EV. Keep it tight: A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes. Dalton Transactions. 2021 May 14;50(18):6003-6033. https://doi.org/10.1039/d1dt00749a

Author

Paderina, Aleksandra V. ; Koshevoy, Igor O. ; Grachova, Elena V. / Keep it tight : A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes. In: Dalton Transactions. 2021 ; Vol. 50, No. 18. pp. 6003-6033.

BibTeX

@article{11fa6973cbf74087aeadf53e969f44ea,
title = "Keep it tight: A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes",
abstract = "Copper subgroup metal ions in the +1 oxidation state are classical candidates for aggregation via non-covalent metal-metal interactions, which are supported by a number of bridging ligands. The bridging phosphines, soft donors with a relatively labile coordination to coinage metals, serve as convenient and essential components of the ligand environment that allow for efficient self-assembly of discrete polynuclear aggregates. Simultaneously, accessible and rich modification of the organic spacer of such P-donors has been used to generate many fascinating structures with attractive photoluminescent behavior. In this work we consider the development of di- and polynuclear complexes of M(i) (M = Cu, Ag, Au) and their photophysical properties, focusing on the effect of phosphine bridging ligands, their flexibility and denticity. ",
author = "Paderina, {Aleksandra V.} and Koshevoy, {Igor O.} and Grachova, {Elena V.}",
note = "Publisher Copyright: {\textcopyright} 2021 The Royal Society of Chemistry. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
day = "14",
doi = "10.1039/d1dt00749a",
language = "English",
volume = "50",
pages = "6003--6033",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "18",

}

RIS

TY - JOUR

T1 - Keep it tight

T2 - A crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AU - Paderina, Aleksandra V.

AU - Koshevoy, Igor O.

AU - Grachova, Elena V.

N1 - Publisher Copyright: © 2021 The Royal Society of Chemistry. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/5/14

Y1 - 2021/5/14

N2 - Copper subgroup metal ions in the +1 oxidation state are classical candidates for aggregation via non-covalent metal-metal interactions, which are supported by a number of bridging ligands. The bridging phosphines, soft donors with a relatively labile coordination to coinage metals, serve as convenient and essential components of the ligand environment that allow for efficient self-assembly of discrete polynuclear aggregates. Simultaneously, accessible and rich modification of the organic spacer of such P-donors has been used to generate many fascinating structures with attractive photoluminescent behavior. In this work we consider the development of di- and polynuclear complexes of M(i) (M = Cu, Ag, Au) and their photophysical properties, focusing on the effect of phosphine bridging ligands, their flexibility and denticity.

AB - Copper subgroup metal ions in the +1 oxidation state are classical candidates for aggregation via non-covalent metal-metal interactions, which are supported by a number of bridging ligands. The bridging phosphines, soft donors with a relatively labile coordination to coinage metals, serve as convenient and essential components of the ligand environment that allow for efficient self-assembly of discrete polynuclear aggregates. Simultaneously, accessible and rich modification of the organic spacer of such P-donors has been used to generate many fascinating structures with attractive photoluminescent behavior. In this work we consider the development of di- and polynuclear complexes of M(i) (M = Cu, Ag, Au) and their photophysical properties, focusing on the effect of phosphine bridging ligands, their flexibility and denticity.

UR - http://www.scopus.com/inward/record.url?scp=85105725845&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/24a8f326-791a-3188-9597-ac0b55ba47a5/

U2 - 10.1039/d1dt00749a

DO - 10.1039/d1dt00749a

M3 - Review article

C2 - 33913991

AN - SCOPUS:85105725845

VL - 50

SP - 6003

EP - 6033

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 18

ER -

ID: 77225916