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The article introduces the reader to the thermodynamic potential of classical thermodynamics, called the J-potential. It can be generally defined as the grand thermodynamic potential plus the volume of the system multiplied by some pressure (which may be the external pressure, the pressure in one of the phases in a multiphase system). Variants of the J-potential are considered. It is shown that the J-potential is perfectly suited for multiphase (heterogeneous) systems. In this work, it is applied to study the dependence of the chemical potential of a substance in a small vapor bubble, formed in the bulk liquid, on the bubble size.
Original languageEnglish
Pages (from-to)250–262
Number of pages13
JournalFine Chemical Engineering
Volume6
Issue number2
DOIs
StatePublished - 23 May 2025

    Scopus subject areas

  • Physical and Theoretical Chemistry
  • Statistical and Nonlinear Physics
  • Surfaces and Interfaces

    Research areas

  • thermodynamic potential, characteristic function, fundamental equations, hybrid thermodynamic potential, J-potential, bubble

ID: 135937477