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Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite, Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2. / Ismagilova, R.M.; Zhitova, E.S.; Zolotarev, A.A.; Krivovichev, S.V.

In: Physics and Chemistry of Minerals, Vol. 46, No. 5, 2019, p. 437-447.

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@article{014236742c734a12ae5651f604fbfe2f,
title = "Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite, Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2.",
abstract = "Thermal behavior of three copper molybdates, lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2 , has been studied by high-temperature X-ray powder diffraction in the temperature range of 25–900 °C. The decomposition of lindgrenite and formation of cupromolybdite were observed at T > 325 °C according to the reaction: Cu 3 (MoO 4 ) 2 (OH) 2 → Cu 3 O(MoO 4 ) 2 + H 2 O. Szenicsite decomposes to cupromolybdite and tenorite at T > 350 °C according to the reaction: 2Cu 3 (MoO 4 )(OH) 4 → Cu 3 O(MoO 4 ) 2 + 3CuO + 2H 2 ↑. Cupromolybdite is stable up to 825 °C. The thermal expansion of lindgrenite, szenicsite and cupromolybdite is strongly an",
author = "R.M. Ismagilova and E.S. Zhitova and A.A. Zolotarev and S.V. Krivovichev",
year = "2019",
language = "English",
volume = "46",
pages = "437--447",
journal = "Physics and Chemistry of Minerals",
issn = "0342-1791",
publisher = "Springer Nature",
number = "5",

}

RIS

TY - JOUR

T1 - Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite, Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2.

AU - Ismagilova, R.M.

AU - Zhitova, E.S.

AU - Zolotarev, A.A.

AU - Krivovichev, S.V.

PY - 2019

Y1 - 2019

N2 - Thermal behavior of three copper molybdates, lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2 , has been studied by high-temperature X-ray powder diffraction in the temperature range of 25–900 °C. The decomposition of lindgrenite and formation of cupromolybdite were observed at T > 325 °C according to the reaction: Cu 3 (MoO 4 ) 2 (OH) 2 → Cu 3 O(MoO 4 ) 2 + H 2 O. Szenicsite decomposes to cupromolybdite and tenorite at T > 350 °C according to the reaction: 2Cu 3 (MoO 4 )(OH) 4 → Cu 3 O(MoO 4 ) 2 + 3CuO + 2H 2 ↑. Cupromolybdite is stable up to 825 °C. The thermal expansion of lindgrenite, szenicsite and cupromolybdite is strongly an

AB - Thermal behavior of three copper molybdates, lindgrenite, Cu 3 (MoO 4 ) 2 (OH) 2 , szenicsite Cu 3 (MoO 4 )(OH) 4 , and cupromolybdite, Cu 3 O(MoO 4 ) 2 , has been studied by high-temperature X-ray powder diffraction in the temperature range of 25–900 °C. The decomposition of lindgrenite and formation of cupromolybdite were observed at T > 325 °C according to the reaction: Cu 3 (MoO 4 ) 2 (OH) 2 → Cu 3 O(MoO 4 ) 2 + H 2 O. Szenicsite decomposes to cupromolybdite and tenorite at T > 350 °C according to the reaction: 2Cu 3 (MoO 4 )(OH) 4 → Cu 3 O(MoO 4 ) 2 + 3CuO + 2H 2 ↑. Cupromolybdite is stable up to 825 °C. The thermal expansion of lindgrenite, szenicsite and cupromolybdite is strongly an

M3 - Article

VL - 46

SP - 437

EP - 447

JO - Physics and Chemistry of Minerals

JF - Physics and Chemistry of Minerals

SN - 0342-1791

IS - 5

ER -

ID: 78411542