Isolated uranyl chromate and polychromate units in crown ether templated compounds

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Isolated uranyl chromate and polychromate units in crown ether templated compounds. / Siidra, Oleg I.; Nazarchuk, Evgeny V.; Sysoeva, Elena V.; Kayukov, Roman A.; Depmeier, Wulf.

In: European Journal of Inorganic Chemistry, Vol. 2014, No. 32, 2014, p. 5495-5498.

Research output: Contribution to journal › Article › peer-review

Author

Siidra, Oleg I. ; Nazarchuk, Evgeny V. ; Sysoeva, Elena V. ; Kayukov, Roman A. ; Depmeier, Wulf. / Isolated uranyl chromate and polychromate units in crown ether templated compounds. In: European Journal of Inorganic Chemistry. 2014 ; Vol. 2014, No. 32. pp. 5495-5498.

BibTeX

@article{f03c1c15b3284cbf94d4821f75337229,

title = "Isolated uranyl chromate and polychromate units in crown ether templated compounds",

abstract = "Two compounds containing isolated uranyl chromate and polychromate units were synthesized through room-temperature reactions of uranyl nitrate, chromium(VI) oxide, and 18-crown-6/15-crown-5 in aqueous solutions. Uranyl chromate with 18-crown-6 consists of neutral ∞ 0[(UO2)(CrO4)(H2O)3] units formed by the bidentate character of the edge sharing UrO5 bipyramid with only CrO4 and organic molecules and no additional crystallization water molecules. Uranyl polychromate with 15-crown-5 is the first inorganic compound in which [CrO4]2-, [Cr2O7]2-, and [Cr3O10]2- chromate groups are observed simultaneously.",

keywords = "Actinides, Chromium, Crown compounds, Polychromates, Structure elucidation",

author = "Siidra, {Oleg I.} and Nazarchuk, {Evgeny V.} and Sysoeva, {Elena V.} and Kayukov, {Roman A.} and Wulf Depmeier",

year = "2014",

doi = "10.1002/ejic.201402806",

language = "English",

volume = "2014",

pages = "5495--5498",

journal = "Berichte der deutschen chemischen Gesellschaft",

issn = "0365-9496",

publisher = "Wiley-Blackwell",

number = "32",

}

RIS

TY - JOUR

T1 - Isolated uranyl chromate and polychromate units in crown ether templated compounds

AU - Siidra, Oleg I.

AU - Nazarchuk, Evgeny V.

AU - Sysoeva, Elena V.

AU - Kayukov, Roman A.

AU - Depmeier, Wulf

PY - 2014

Y1 - 2014

N2 - Two compounds containing isolated uranyl chromate and polychromate units were synthesized through room-temperature reactions of uranyl nitrate, chromium(VI) oxide, and 18-crown-6/15-crown-5 in aqueous solutions. Uranyl chromate with 18-crown-6 consists of neutral ∞ 0[(UO2)(CrO4)(H2O)3] units formed by the bidentate character of the edge sharing UrO5 bipyramid with only CrO4 and organic molecules and no additional crystallization water molecules. Uranyl polychromate with 15-crown-5 is the first inorganic compound in which [CrO4]2-, [Cr2O7]2-, and [Cr3O10]2- chromate groups are observed simultaneously.

AB - Two compounds containing isolated uranyl chromate and polychromate units were synthesized through room-temperature reactions of uranyl nitrate, chromium(VI) oxide, and 18-crown-6/15-crown-5 in aqueous solutions. Uranyl chromate with 18-crown-6 consists of neutral ∞ 0[(UO2)(CrO4)(H2O)3] units formed by the bidentate character of the edge sharing UrO5 bipyramid with only CrO4 and organic molecules and no additional crystallization water molecules. Uranyl polychromate with 15-crown-5 is the first inorganic compound in which [CrO4]2-, [Cr2O7]2-, and [Cr3O10]2- chromate groups are observed simultaneously.

KW - Actinides

KW - Chromium

KW - Crown compounds

KW - Polychromates

KW - Structure elucidation

UR - http://www.scopus.com/inward/record.url?scp=84982066731&partnerID=8YFLogxK

U2 - 10.1002/ejic.201402806

DO - 10.1002/ejic.201402806

M3 - Article

AN - SCOPUS:84982066731

VL - 2014

SP - 5495

EP - 5498

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 32

ER -

ID: 9144762