Research output: Contribution to journal › Article › peer-review
The heat capacities of protonated layered perovskite-like oxides H1.64K0.36Nd2Ti3O10·0.61 H2O and H1.89K0.11Nd2Ti3O10·0.60 H2O were measured by precision adiabatic vacuum calorimetry over the temperature range of (6–300) K. The standard thermodynamic functions: molar heat capacity, enthalpy, entropy, and the Gibbs energy of the compounds were evaluated from the experimental data of the heat capacities over the temperature range of T = (6–300) K. The deviation of experimental points from fitting curves obtained on the basis of Debye's theory. The overview on low-temperature heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like titanates NaLnTiO4 and A2Ln2Ti3O10 (A=H, Na, K; Ln=La, Nd, Gd) is present.
Original language | English |
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Article number | 178533 |
Number of pages | 7 |
Journal | Thermochimica Acta |
Volume | 686 |
DOIs | |
State | Published - Apr 2020 |
ID: 70816895