• Anna M. Sankovich
  • Tatiana D. Myshkovskaia
  • Alexey V. Markin
  • Natalia N. Smirnova
  • Irina A. Zvereva

The heat capacities of protonated layered perovskite-like oxides H1.64K0.36Nd2Ti3O10·0.61 H2O and H1.89K0.11Nd2Ti3O10·0.60 H2O were measured by precision adiabatic vacuum calorimetry over the temperature range of (6–300) K. The standard thermodynamic functions: molar heat capacity, enthalpy, entropy, and the Gibbs energy of the compounds were evaluated from the experimental data of the heat capacities over the temperature range of T = (6–300) K. The deviation of experimental points from fitting curves obtained on the basis of Debye's theory. The overview on low-temperature heat capacity and standard thermodynamic properties of cation-ordered layered perovskite-like titanates NaLnTiO4 and A2Ln2Ti3O10 (A=H, Na, K; Ln=La, Nd, Gd) is present.

Original languageEnglish
Article number178533
Number of pages7
JournalThermochimica Acta
Volume686
DOIs
StatePublished - Apr 2020

    Scopus subject areas

  • Condensed Matter Physics
  • Instrumentation
  • Physical and Theoretical Chemistry

    Research areas

  • Adiabatic calorimetry, Heat capacity, Layered perovskite-like oxides, Protonated forms, Standard thermodynamic functions, MOBILITY, K2LA2TI3O10, RANGE

ID: 70816895