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Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors. / Паршина, Елизавета Кирилловна; Дерябин, Константин Валерьевич; Колесников, Илья Евгеньевич; Новиков, Александр Сергеевич; Кочева, Анастасия Никитична; Головенко, Екатерина Алексеевна; Исламова, Регина Маратовна.

In: Macromolecular Rapid Communications, Vol. 45, No. 21, 2400450, 01.11.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Паршина, ЕК, Дерябин, КВ, Колесников, ИЕ, Новиков, АС, Кочева, АН, Головенко, ЕА & Исламова, РМ 2024, 'Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors', Macromolecular Rapid Communications, vol. 45, no. 21, 2400450. https://doi.org/10.1002/marc.202400450

APA

Паршина, Е. К., Дерябин, К. В., Колесников, И. Е., Новиков, А. С., Кочева, А. Н., Головенко, Е. А., & Исламова, Р. М. (2024). Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors. Macromolecular Rapid Communications, 45(21), [2400450]. https://doi.org/10.1002/marc.202400450

Vancouver

Паршина ЕК, Дерябин КВ, Колесников ИЕ, Новиков АС, Кочева АН, Головенко ЕА et al. Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors. Macromolecular Rapid Communications. 2024 Nov 1;45(21). 2400450. https://doi.org/10.1002/marc.202400450

Author

Паршина, Елизавета Кирилловна ; Дерябин, Константин Валерьевич ; Колесников, Илья Евгеньевич ; Новиков, Александр Сергеевич ; Кочева, Анастасия Никитична ; Головенко, Екатерина Алексеевна ; Исламова, Регина Маратовна. / Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors. In: Macromolecular Rapid Communications. 2024 ; Vol. 45, No. 21.

BibTeX

@article{31bca20fb39c45e8b1fa54e7cc69ce16,
title = "Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors",
abstract = "Polymer-metal complexes (PMCs) based on poly(2,2′-bipyridine-4,4′-dicarboxamide-co-polydimethylsiloxanes) with cyclometalated di(2-phenylpyridinato-C2,N')iridium(III) fragments and cross-linked by Zn2+ (Zn[Ir]-BipyPDMSs) or Ir3+ (Ir[Ir]-BipyPDMSs) represent flexible, stretchable, phosphorescent, and self-healing molecular oxygen sensors. PMCs provide strong phosphorescence at λem = 595–605 nm. Zn[Ir]-BipyPDMS with PDMS chain length of Mn = 5000 has the highest quantum yield of 9.3% and is a molecular oxygen sensor at different O2 concentrations (0–100 vol%) compared to Ir[Ir]-BipyPDMSs. A Stern−Volmer constant is determined for Zn[Ir]-BipyPDMS as KSV = 0.014%−1, which is similar to the reported oxygen-sensitive iridium(III) complexes. All synthesized PMCs exhibit high elongation at break (up to 1100%) and self-healing efficiency (up to 99%).",
keywords = "iridium(III), oxygen sensors, photoluminescence, polysiloxanes, self-healing",
author = "Паршина, {Елизавета Кирилловна} and Дерябин, {Константин Валерьевич} and Колесников, {Илья Евгеньевич} and Новиков, {Александр Сергеевич} and Кочева, {Анастасия Никитична} and Головенко, {Екатерина Алексеевна} and Исламова, {Регина Маратовна}",
year = "2024",
month = nov,
day = "1",
doi = "10.1002/marc.202400450",
language = "English",
volume = "45",
journal = "Macromolecular Rapid Communications",
issn = "1022-1336",
publisher = "Wiley-Blackwell",
number = "21",

}

RIS

TY - JOUR

T1 - Iridium(III)-incorporating self-healing polysiloxanes as materials for light-emitting oxygen sensors

AU - Паршина, Елизавета Кирилловна

AU - Дерябин, Константин Валерьевич

AU - Колесников, Илья Евгеньевич

AU - Новиков, Александр Сергеевич

AU - Кочева, Анастасия Никитична

AU - Головенко, Екатерина Алексеевна

AU - Исламова, Регина Маратовна

PY - 2024/11/1

Y1 - 2024/11/1

N2 - Polymer-metal complexes (PMCs) based on poly(2,2′-bipyridine-4,4′-dicarboxamide-co-polydimethylsiloxanes) with cyclometalated di(2-phenylpyridinato-C2,N')iridium(III) fragments and cross-linked by Zn2+ (Zn[Ir]-BipyPDMSs) or Ir3+ (Ir[Ir]-BipyPDMSs) represent flexible, stretchable, phosphorescent, and self-healing molecular oxygen sensors. PMCs provide strong phosphorescence at λem = 595–605 nm. Zn[Ir]-BipyPDMS with PDMS chain length of Mn = 5000 has the highest quantum yield of 9.3% and is a molecular oxygen sensor at different O2 concentrations (0–100 vol%) compared to Ir[Ir]-BipyPDMSs. A Stern−Volmer constant is determined for Zn[Ir]-BipyPDMS as KSV = 0.014%−1, which is similar to the reported oxygen-sensitive iridium(III) complexes. All synthesized PMCs exhibit high elongation at break (up to 1100%) and self-healing efficiency (up to 99%).

AB - Polymer-metal complexes (PMCs) based on poly(2,2′-bipyridine-4,4′-dicarboxamide-co-polydimethylsiloxanes) with cyclometalated di(2-phenylpyridinato-C2,N')iridium(III) fragments and cross-linked by Zn2+ (Zn[Ir]-BipyPDMSs) or Ir3+ (Ir[Ir]-BipyPDMSs) represent flexible, stretchable, phosphorescent, and self-healing molecular oxygen sensors. PMCs provide strong phosphorescence at λem = 595–605 nm. Zn[Ir]-BipyPDMS with PDMS chain length of Mn = 5000 has the highest quantum yield of 9.3% and is a molecular oxygen sensor at different O2 concentrations (0–100 vol%) compared to Ir[Ir]-BipyPDMSs. A Stern−Volmer constant is determined for Zn[Ir]-BipyPDMS as KSV = 0.014%−1, which is similar to the reported oxygen-sensitive iridium(III) complexes. All synthesized PMCs exhibit high elongation at break (up to 1100%) and self-healing efficiency (up to 99%).

KW - iridium(III)

KW - oxygen sensors

KW - photoluminescence

KW - polysiloxanes

KW - self-healing

UR - https://www.mendeley.com/catalogue/c232e44c-620c-3421-af09-c86e6690c8cb/

U2 - 10.1002/marc.202400450

DO - 10.1002/marc.202400450

M3 - Article

VL - 45

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

SN - 1022-1336

IS - 21

M1 - 2400450

ER -

ID: 122217112