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Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4. / Mikhailichenko, T. V.; Kalinina, L. A.; Ushakova, Yu N.; Murin, I. V.

In: Russian Journal of Electrochemistry, Vol. 49, No. 8, 08.2013, p. 776-782.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhailichenko, TV, Kalinina, LA, Ushakova, YN & Murin, IV 2013, 'Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4', Russian Journal of Electrochemistry, vol. 49, no. 8, pp. 776-782. https://doi.org/10.1134/S1023193513080132, https://doi.org/10.1134/S1023193513080132

APA

Mikhailichenko, T. V., Kalinina, L. A., Ushakova, Y. N., & Murin, I. V. (2013). Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4. Russian Journal of Electrochemistry, 49(8), 776-782. https://doi.org/10.1134/S1023193513080132, https://doi.org/10.1134/S1023193513080132

Vancouver

Mikhailichenko TV, Kalinina LA, Ushakova YN, Murin IV. Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4. Russian Journal of Electrochemistry. 2013 Aug;49(8):776-782. https://doi.org/10.1134/S1023193513080132, https://doi.org/10.1134/S1023193513080132

Author

Mikhailichenko, T. V. ; Kalinina, L. A. ; Ushakova, Yu N. ; Murin, I. V. / Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4. In: Russian Journal of Electrochemistry. 2013 ; Vol. 49, No. 8. pp. 776-782.

BibTeX

@article{32edc207dde541b6bc8b316f987b1824,
title = "Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4",
abstract = "Solid solutions of Sm2S3 and Tm2S 3 based on BaSm2S4 (the structural type of CaFe2O4) are obtained. The samples are studied using microprobe analysis and the XRD technique. The length of the solid solution region is determined. The type of ion conductivity and thermodynamics of dissolution of the binary sulfides of Sm2S3 and Tm 2S3 in BaSm2S4 are studied. Partial molar enthalpies of dissolution of binary sulfides in basic thiosamarate are determined. A possible mechanism of defect formation is suggested.",
keywords = "barium thiosamarate, mechanism of defect formation, modified EMF technique, samarium sulfide, solid electrolytes, thulium sulfide",
author = "Mikhailichenko, {T. V.} and Kalinina, {L. A.} and Ushakova, {Yu N.} and Murin, {I. V.}",
year = "2013",
month = aug,
doi = "10.1134/S1023193513080132",
language = "English",
volume = "49",
pages = "776--782",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "8",

}

RIS

TY - JOUR

T1 - Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm 2S4

AU - Mikhailichenko, T. V.

AU - Kalinina, L. A.

AU - Ushakova, Yu N.

AU - Murin, I. V.

PY - 2013/8

Y1 - 2013/8

N2 - Solid solutions of Sm2S3 and Tm2S 3 based on BaSm2S4 (the structural type of CaFe2O4) are obtained. The samples are studied using microprobe analysis and the XRD technique. The length of the solid solution region is determined. The type of ion conductivity and thermodynamics of dissolution of the binary sulfides of Sm2S3 and Tm 2S3 in BaSm2S4 are studied. Partial molar enthalpies of dissolution of binary sulfides in basic thiosamarate are determined. A possible mechanism of defect formation is suggested.

AB - Solid solutions of Sm2S3 and Tm2S 3 based on BaSm2S4 (the structural type of CaFe2O4) are obtained. The samples are studied using microprobe analysis and the XRD technique. The length of the solid solution region is determined. The type of ion conductivity and thermodynamics of dissolution of the binary sulfides of Sm2S3 and Tm 2S3 in BaSm2S4 are studied. Partial molar enthalpies of dissolution of binary sulfides in basic thiosamarate are determined. A possible mechanism of defect formation is suggested.

KW - barium thiosamarate

KW - mechanism of defect formation

KW - modified EMF technique

KW - samarium sulfide

KW - solid electrolytes

KW - thulium sulfide

UR - http://www.scopus.com/inward/record.url?scp=84882744964&partnerID=8YFLogxK

U2 - 10.1134/S1023193513080132

DO - 10.1134/S1023193513080132

M3 - Article

VL - 49

SP - 776

EP - 782

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 8

ER -

ID: 7396515