Research output: Contribution to journal › Article › peer-review
Iodonium cation stabilizes square-planar configuration of the silver(I) tetratriflate. / Юнусова, Севиля Наильевна; Новиков, Александр Сергеевич; Болотин, Дмитрий Сергеевич; Ильин, Михаил Вячеславович.
In: Inorganica Chimica Acta, Vol. 568, 122079, 01.08.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Iodonium cation stabilizes square-planar configuration of the silver(I) tetratriflate
AU - Юнусова, Севиля Наильевна
AU - Новиков, Александр Сергеевич
AU - Болотин, Дмитрий Сергеевич
AU - Ильин, Михаил Вячеславович
PY - 2024/8/1
Y1 - 2024/8/1
N2 - In this work, we have experimentally and theoretically shown that halogen bonding can stabilize the rare example of square-planar configuration of the silver(I) center. The crystallographic analysis of tris-dibenziodolium silver(I) tetratriflate reveals two types of halogen bonding interactions between the triflate ligands and the dibenziodolium cation, which might stabilize the such square-planar coordination geometry. Theoretical calculations confirm the noncovalent nature of the I⋅⋅⋅O contacts and provide insights into their electronic properties.
AB - In this work, we have experimentally and theoretically shown that halogen bonding can stabilize the rare example of square-planar configuration of the silver(I) center. The crystallographic analysis of tris-dibenziodolium silver(I) tetratriflate reveals two types of halogen bonding interactions between the triflate ligands and the dibenziodolium cation, which might stabilize the such square-planar coordination geometry. Theoretical calculations confirm the noncovalent nature of the I⋅⋅⋅O contacts and provide insights into their electronic properties.
KW - Halogen bond
KW - Noncovalent interactions
KW - Square-planar silver(I) complex
UR - https://www.mendeley.com/catalogue/d0a405b4-dd03-34b1-96af-40be759096bf/
U2 - 10.1016/j.ica.2024.122079
DO - 10.1016/j.ica.2024.122079
M3 - Article
VL - 568
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 122079
ER -
ID: 119244368