Research output: Contribution to journal › Article › peer-review
Investigation of structure of GeS1.35 glasses with the use of isotopically enriched germanium and Raman scattering spectroscopy. / Pan'kin, D. V.; Tver'yanovich, Yu S.; Churbanov, F.
In: Journal of Non-Crystalline Solids, Vol. 457, 01.02.2017, p. 164-168.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Investigation of structure of GeS1.35 glasses with the use of isotopically enriched germanium and Raman scattering spectroscopy
AU - Pan'kin, D. V.
AU - Tver'yanovich, Yu S.
AU - Churbanov, F.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - The samples of GeS1.35 glasses were synthesized with germanium and sulfur of natural isotopic composition and with isotopically enriched germanium (72Ge, 74Ge, 76Ge). The glasses were investigated by the method of Raman scattering spectroscopy (RSS). It was shown that GeS4/2 tetrahedrons and structural units containing Ge[sbnd]Ge homobonds are present in glasses. The quantum-mechanical calculation of the frequency of fundamental vibrational modes in glass network was carried out. Their dependencies on the atomic mass of germanium were used for identification of bands in RS (Raman scattering) spectra.
AB - The samples of GeS1.35 glasses were synthesized with germanium and sulfur of natural isotopic composition and with isotopically enriched germanium (72Ge, 74Ge, 76Ge). The glasses were investigated by the method of Raman scattering spectroscopy (RSS). It was shown that GeS4/2 tetrahedrons and structural units containing Ge[sbnd]Ge homobonds are present in glasses. The quantum-mechanical calculation of the frequency of fundamental vibrational modes in glass network was carried out. Their dependencies on the atomic mass of germanium were used for identification of bands in RS (Raman scattering) spectra.
KW - Chalcogenide glasses
KW - Monoisotopic glasses
KW - Raman scattering spectroscopy
KW - Structure of glasses
UR - http://www.scopus.com/inward/record.url?scp=85003691554&partnerID=8YFLogxK
U2 - 10.1016/j.jnoncrysol.2016.11.038
DO - 10.1016/j.jnoncrysol.2016.11.038
M3 - Article
AN - SCOPUS:85003691554
VL - 457
SP - 164
EP - 168
JO - Journal of Non-Crystalline Solids
JF - Journal of Non-Crystalline Solids
SN - 0022-3093
ER -
ID: 32917113