Research output: Contribution to journal › Article › peer-review
Intermolecular interactions and correlation between optical transitions in different molecules. / Kouzov, Alexandre P.
In: Journal of Molecular Liquids, Vol. 70, No. 2-3 SPEC. ISS., 01.01.1996, p. 133-142.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Intermolecular interactions and correlation between optical transitions in different molecules
AU - Kouzov, Alexandre P.
PY - 1996/1/1
Y1 - 1996/1/1
N2 - An exact treatment of the interaction-induced correlations between optical transitions in different molecules is presented. In a pure fluid (or in its buffer solution), the correlation terms are found to be additive with the conventional relaxation matrix elements. Same projection approach is used to study similar effects for molecules belonging to different species a and b. An exact solution derived for binary mixtures is used to analyze the cross (ab)-terms in the case of two-line mixing. At the binary collision regime, new spectral features of higher orders in density may appear due to the intermolecular optical transition coherence.
AB - An exact treatment of the interaction-induced correlations between optical transitions in different molecules is presented. In a pure fluid (or in its buffer solution), the correlation terms are found to be additive with the conventional relaxation matrix elements. Same projection approach is used to study similar effects for molecules belonging to different species a and b. An exact solution derived for binary mixtures is used to analyze the cross (ab)-terms in the case of two-line mixing. At the binary collision regime, new spectral features of higher orders in density may appear due to the intermolecular optical transition coherence.
UR - http://www.scopus.com/inward/record.url?scp=0040555475&partnerID=8YFLogxK
U2 - 10.1016/0167-7322(96)00963-4
DO - 10.1016/0167-7322(96)00963-4
M3 - Article
AN - SCOPUS:0040555475
VL - 70
SP - 133
EP - 142
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
SN - 0167-7322
IS - 2-3 SPEC. ISS.
ER -
ID: 104351516