The problem of using the chemical potential of a solid in interfacial thermodynamics and the anisotropy of chemical potential is discussed. A (typical for solids) difference between surface-free energy and surface tension is shown to be the consequence of non-uniformity of chemical potential in a solid interface. A generalized adsorption equation is formulated for deformable solids.

Original languageEnglish
Pages (from-to)275-279
Number of pages5
JournalSolid State Ionics
Volume75
Issue numberC
DOIs
StatePublished - Jan 1995

    Research areas

  • Anisotropy, Interfacial thermodynamics

    Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

ID: 95721656